The reaction of Na[H2B(Mt)2] (mt = methimazolyl) with [AuBr(PEt3)] provides [Au{H2B(mt)2}(PEt 3)], which reacts with [Mo(CO)3(NCMe)3] or [Mo(CO)3(η6-C7H8)] to provide the bimetallic salt [Mo2{μ2H2B(mt) 2}(CO)7][Au2{,μ2-H 2B(mt)2}](PEt3)2], featuring t
Reaction of Na[Mo(CO)(3)(eta(5)-C5H5)] with CoCl(PPh(3))(3) in tetrahydrofuran under 1 atm of CO yie...
Thiocarbamoyl complexes [Mo(eta(2)-SCNMe2)-(CO)(2){HnB(mt)(4-n)}] (n = 1, 2) are obtained from the r...
We report herein the synthesis of a bisphosphine-[NHC-BH3] compound and its coordination toward gold...
Molybdenum stannyl complexes ligated by poly(methimazolyl)borate ligands are accessible via compleme...
Molybdenum stannyl complexes ligated by poly(methimazolyl)borate ligands are accessible via compleme...
The reactions of [M(η3-C3H5)Br(CO)2(NCMe)2] (M = Mo, W) or [Mo(η3-C3H5)Br(CO)2(PMe2Ph)2] with Na[H2B...
The prolonged reaction of [Rh{B(mt)3}(η4C 8H12)]Cl, prepared from [Rh(η4-C 8H12)Cl]2 and 2 equiv of ...
The reactions of [M(≡CC6H2Me 3-2,4,6)X(CO)2(L)2] (M = Mo, W; X = Cl, Br; L = pyridine, 3,5-dimethylp...
Synthetic routes are reported to complexes of the form [MI-(alkyne)(CO) {HnB(mt)4-n}] (mt = methimaz...
The complexes [Pd{κ2-S,S′-H2B(mimMe)2}(η3-C3H4R)] (R = H, Me) have been obtained in high yield from ...
The reactions of Na[HB(mt)3] (mt = methimazolyl) with [Ta(η2-RC≡CR)Cl3(dme)] (R = Ph, Et) provide th...
The reaction of iodotrimethylplatinum(IV) with 1 equiv of Na[HB(mt) 3] or Na[H2B(mt)2] (mt = methima...
The reaction kinetics of HnB(mt)4-n salts with high oxidation state titanium complexes of Dihydrobys...
The reactions of [M(η3 -C3H5)Br(CO)2(NCMe)2] (M = Mo, W) or [Mo(η3 -C3H5)Br(CO)2(PMe2Ph)2] with Na...
International audienceA series of new bis(σ)borate and agostic complexes of group 7 metals have been...
Reaction of Na[Mo(CO)(3)(eta(5)-C5H5)] with CoCl(PPh(3))(3) in tetrahydrofuran under 1 atm of CO yie...
Thiocarbamoyl complexes [Mo(eta(2)-SCNMe2)-(CO)(2){HnB(mt)(4-n)}] (n = 1, 2) are obtained from the r...
We report herein the synthesis of a bisphosphine-[NHC-BH3] compound and its coordination toward gold...
Molybdenum stannyl complexes ligated by poly(methimazolyl)borate ligands are accessible via compleme...
Molybdenum stannyl complexes ligated by poly(methimazolyl)borate ligands are accessible via compleme...
The reactions of [M(η3-C3H5)Br(CO)2(NCMe)2] (M = Mo, W) or [Mo(η3-C3H5)Br(CO)2(PMe2Ph)2] with Na[H2B...
The prolonged reaction of [Rh{B(mt)3}(η4C 8H12)]Cl, prepared from [Rh(η4-C 8H12)Cl]2 and 2 equiv of ...
The reactions of [M(≡CC6H2Me 3-2,4,6)X(CO)2(L)2] (M = Mo, W; X = Cl, Br; L = pyridine, 3,5-dimethylp...
Synthetic routes are reported to complexes of the form [MI-(alkyne)(CO) {HnB(mt)4-n}] (mt = methimaz...
The complexes [Pd{κ2-S,S′-H2B(mimMe)2}(η3-C3H4R)] (R = H, Me) have been obtained in high yield from ...
The reactions of Na[HB(mt)3] (mt = methimazolyl) with [Ta(η2-RC≡CR)Cl3(dme)] (R = Ph, Et) provide th...
The reaction of iodotrimethylplatinum(IV) with 1 equiv of Na[HB(mt) 3] or Na[H2B(mt)2] (mt = methima...
The reaction kinetics of HnB(mt)4-n salts with high oxidation state titanium complexes of Dihydrobys...
The reactions of [M(η3 -C3H5)Br(CO)2(NCMe)2] (M = Mo, W) or [Mo(η3 -C3H5)Br(CO)2(PMe2Ph)2] with Na...
International audienceA series of new bis(σ)borate and agostic complexes of group 7 metals have been...
Reaction of Na[Mo(CO)(3)(eta(5)-C5H5)] with CoCl(PPh(3))(3) in tetrahydrofuran under 1 atm of CO yie...
Thiocarbamoyl complexes [Mo(eta(2)-SCNMe2)-(CO)(2){HnB(mt)(4-n)}] (n = 1, 2) are obtained from the r...
We report herein the synthesis of a bisphosphine-[NHC-BH3] compound and its coordination toward gold...