The reactions of [Mo(≡CCI)(CO)2{HB(pzMe2) 3]] (pz = 3,5-dimethylpyrazol-1-yl) with lithium alkynylselenolates (LiSeC=CR; R = CMe3, SiMe3) provide the alkynylselenolatoalkylidyne complexes [Mo(≡CSeC≡CR)(CO) 2{HB(pzMe2)3}]. Cobalt carbonyl adds acros
Reaction of Li(3,5-R(2)-pyrazolide) (R = tBu or Ph, dXpz) with Mo(NAr)(CHCMe(2)Ph)(OTf)(2)(DME) yiel...
Alkyl compounds of cobalt(II) containing aryl-substituted N-heterocyclic carbene ligands have been ...
Synthetic routes are reported to complexes of the form [MI-(alkyne)(CO) {HnB(mt)4-n}] (mt = methimaz...
The reactions of [M(≡CX)(CO)2{HB(pzMe2) 3}] (M = Mo, W; X = Cl, Br; pz = pyrazol-1-yl) with "BuLi pr...
The successive treatment of [Mo(≡CBr)(CO)2{HB(pzMe2)3}] (1; pz = pyrazol-1-yl) withnBuLi and B(OR)3 ...
International audienceThe dicobalt alkyne complex [Co2(μ-PhC≢CH)(CO)6] 1a reacted with [Mo2(η5-C5H5)...
The successive treatment of terminal alkynes, HC≡CR (R = C6H4Me-4, SiMe3), withnBuLi and gray seleni...
The reaction of [W(≡CR)(CO)2(η-C5H5)] (R = C6H3Me2-2,6) with thionyl chloride provides the metallacy...
The sequential treatment of [Mo(≡CBr)(CO)2{HB(pzMe 2)3}] (pz = pyrazol-1-yl) with nBuLi and ClBR2 (B...
The reactions of the bromocarbyne complex [Mo(≡CBr)(CO) 2[HB(pzMe2)3}] (pz = pyrazol-1-yl) with a ra...
The reactions of [M(≡CC6H2Me 3-2,4,6)X(CO)2(L)2] (M = Mo, W; X = Cl, Br; L = pyridine, 3,5-dimethylp...
The reactions of the complexes [Mo(CO)2(η4-C4Ph4CO)2] and [Mo(CO)3(NCMe)(η4-C4Ph4CO)] with the alkyn...
Synthetic routes to thiocarbamoyl (thiocarboxamide) complexes of divalent molybdenum and tungsten ar...
The reactions of the germylenoid Li(THF)<sub>3</sub>GeCl<sub>2</sub>C(SiMe<sub>3</sub>)<sub>3</sub...
The reactions of [M(η3-C3H5)Br(CO)2(NCMe)2] (M = Mo, W) or [Mo(η3-C3H5)Br(CO)2(PMe2Ph)2] with Na[H2B...
Reaction of Li(3,5-R(2)-pyrazolide) (R = tBu or Ph, dXpz) with Mo(NAr)(CHCMe(2)Ph)(OTf)(2)(DME) yiel...
Alkyl compounds of cobalt(II) containing aryl-substituted N-heterocyclic carbene ligands have been ...
Synthetic routes are reported to complexes of the form [MI-(alkyne)(CO) {HnB(mt)4-n}] (mt = methimaz...
The reactions of [M(≡CX)(CO)2{HB(pzMe2) 3}] (M = Mo, W; X = Cl, Br; pz = pyrazol-1-yl) with "BuLi pr...
The successive treatment of [Mo(≡CBr)(CO)2{HB(pzMe2)3}] (1; pz = pyrazol-1-yl) withnBuLi and B(OR)3 ...
International audienceThe dicobalt alkyne complex [Co2(μ-PhC≢CH)(CO)6] 1a reacted with [Mo2(η5-C5H5)...
The successive treatment of terminal alkynes, HC≡CR (R = C6H4Me-4, SiMe3), withnBuLi and gray seleni...
The reaction of [W(≡CR)(CO)2(η-C5H5)] (R = C6H3Me2-2,6) with thionyl chloride provides the metallacy...
The sequential treatment of [Mo(≡CBr)(CO)2{HB(pzMe 2)3}] (pz = pyrazol-1-yl) with nBuLi and ClBR2 (B...
The reactions of the bromocarbyne complex [Mo(≡CBr)(CO) 2[HB(pzMe2)3}] (pz = pyrazol-1-yl) with a ra...
The reactions of [M(≡CC6H2Me 3-2,4,6)X(CO)2(L)2] (M = Mo, W; X = Cl, Br; L = pyridine, 3,5-dimethylp...
The reactions of the complexes [Mo(CO)2(η4-C4Ph4CO)2] and [Mo(CO)3(NCMe)(η4-C4Ph4CO)] with the alkyn...
Synthetic routes to thiocarbamoyl (thiocarboxamide) complexes of divalent molybdenum and tungsten ar...
The reactions of the germylenoid Li(THF)<sub>3</sub>GeCl<sub>2</sub>C(SiMe<sub>3</sub>)<sub>3</sub...
The reactions of [M(η3-C3H5)Br(CO)2(NCMe)2] (M = Mo, W) or [Mo(η3-C3H5)Br(CO)2(PMe2Ph)2] with Na[H2B...
Reaction of Li(3,5-R(2)-pyrazolide) (R = tBu or Ph, dXpz) with Mo(NAr)(CHCMe(2)Ph)(OTf)(2)(DME) yiel...
Alkyl compounds of cobalt(II) containing aryl-substituted N-heterocyclic carbene ligands have been ...
Synthetic routes are reported to complexes of the form [MI-(alkyne)(CO) {HnB(mt)4-n}] (mt = methimaz...