The sequential treatment of [Mo(≡CBr)(CO)2{HB(pzMe 2)3}] (pz = pyrazol-1-yl) with nBuLi and ClBR2 (BR2 = B(NMe2)2, O 2C6H4) in tetrahydrofuran provides the borylcarbyne complexes [Mo(≡CBR2)(CO)2{HB(pzMe 2)3}], in contrast to the reactions of many hal
A lithiocarbyne complex Tp*(CO){u2082}Mo{u2261}CLi (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate)...
The reactions of [Mo(≡CCI)(CO)2{HB(pzMe2) 3]] (pz = 3,5-dimethylpyrazol-1-yl) with lithium alkynylse...
The synthesis and characterization of iron and manganese complexes containing the tetrachlorocatecho...
The reactions of the bromocarbyne complex [Mo(≡CBr)(CO) 2[HB(pzMe2)3}] (pz = pyrazol-1-yl) with a ra...
The reactions of [M(η3-C3H5)Br(CO)2(NCMe)2] (M = Mo, W) or [Mo(η3-C3H5)Br(CO)2(PMe2Ph)2] with Na[H2B...
The successive treatment of [Mo(≡CBr)(CO)2{HB(pzMe2)3}] (1; pz = pyrazol-1-yl) withnBuLi and B(OR)3 ...
The successive reactions of [Mo(≡CBr)(CO)2(Tp*)] (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate) w...
The reactions of [M(η3 -C3H5)Br(CO)2(NCMe)2] (M = Mo, W) or [Mo(η3 -C3H5)Br(CO)2(PMe2Ph)2] with Na...
cited By 28International audienceThe reaction of mono- or dichloro-dimolybdenum(m) complexes [Mo 2Cp...
Synthetic routes are reported to complexes of the form [MI-(alkyne)(CO) {HnB(mt)4-n}] (mt = methimaz...
Durch Umsetzung von monoanionischen Carbonylaten mit Bortrihalogeniden lassen sich Dihalogenborylkom...
Summarization: Reaction of [HB(bdmpz),] , obtained by reaction of 4-benzyl-3,5-dimethylpyrazole (Hbd...
Thiocarbamoyl complexes [Mo(eta(2)-SCNMe2)-(CO)(2){HnB(mt)(4-n)}] (n = 1, 2) are obtained from the r...
The new molybdenum imido alkylidene complex Mo(N(2,6-<i>i</i>Pr<sub>2</sub>C<sub>6</sub>H<sub>3</s...
The phosphinocarbyne complex [Mo(≡CPPh2)(CO)2{HB(pzMe 2)3}] is obtained by successive treatment of [...
A lithiocarbyne complex Tp*(CO){u2082}Mo{u2261}CLi (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate)...
The reactions of [Mo(≡CCI)(CO)2{HB(pzMe2) 3]] (pz = 3,5-dimethylpyrazol-1-yl) with lithium alkynylse...
The synthesis and characterization of iron and manganese complexes containing the tetrachlorocatecho...
The reactions of the bromocarbyne complex [Mo(≡CBr)(CO) 2[HB(pzMe2)3}] (pz = pyrazol-1-yl) with a ra...
The reactions of [M(η3-C3H5)Br(CO)2(NCMe)2] (M = Mo, W) or [Mo(η3-C3H5)Br(CO)2(PMe2Ph)2] with Na[H2B...
The successive treatment of [Mo(≡CBr)(CO)2{HB(pzMe2)3}] (1; pz = pyrazol-1-yl) withnBuLi and B(OR)3 ...
The successive reactions of [Mo(≡CBr)(CO)2(Tp*)] (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate) w...
The reactions of [M(η3 -C3H5)Br(CO)2(NCMe)2] (M = Mo, W) or [Mo(η3 -C3H5)Br(CO)2(PMe2Ph)2] with Na...
cited By 28International audienceThe reaction of mono- or dichloro-dimolybdenum(m) complexes [Mo 2Cp...
Synthetic routes are reported to complexes of the form [MI-(alkyne)(CO) {HnB(mt)4-n}] (mt = methimaz...
Durch Umsetzung von monoanionischen Carbonylaten mit Bortrihalogeniden lassen sich Dihalogenborylkom...
Summarization: Reaction of [HB(bdmpz),] , obtained by reaction of 4-benzyl-3,5-dimethylpyrazole (Hbd...
Thiocarbamoyl complexes [Mo(eta(2)-SCNMe2)-(CO)(2){HnB(mt)(4-n)}] (n = 1, 2) are obtained from the r...
The new molybdenum imido alkylidene complex Mo(N(2,6-<i>i</i>Pr<sub>2</sub>C<sub>6</sub>H<sub>3</s...
The phosphinocarbyne complex [Mo(≡CPPh2)(CO)2{HB(pzMe 2)3}] is obtained by successive treatment of [...
A lithiocarbyne complex Tp*(CO){u2082}Mo{u2261}CLi (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate)...
The reactions of [Mo(≡CCI)(CO)2{HB(pzMe2) 3]] (pz = 3,5-dimethylpyrazol-1-yl) with lithium alkynylse...
The synthesis and characterization of iron and manganese complexes containing the tetrachlorocatecho...