The tungsten isotopic composition of Eoarchean rocks: Implications for early silicate differentiation and core-mantle interaction on Earth

We have measured182W/184W for Eoarchean rocks from the Itsaq Gneiss Complex (3.8-3.7 Ga pillow meta-basalts, a meta-tonalite, and meta-sediments) and Acasta Gneiss Complex (4.0-3.6 Ga felsic orthogneisses) to assess possible W isotopic heterogeneity within the silicate Earth and to constrain W isotopic evolution of the mantle. The data reveal that182W/184W values in the Eoarchean samples are uniform within the analytical error and indistinguishable from the modern accessible mantle signature, suggesting that the W isotopic composition of the upper mantle has not changed significantly since the Eoarchean era. The results imply either that chemical communication between the mantle and core has been insignificant in post-Hadean times, or that a lowermost mantle with a distinctive W isotope signature has been isolated from mantle convective cycling. Most terrestrial rock samples have a 0.2ε 142Nd/144Nd higher than the chondrite average. This requires either the presence of a hidden enriched reservoir formed within the first 30 Ma of the Solar System, or the bulk Earth having a ∼ 5% higher Sm/Nd than the chondrite average. We explored the relevance of the182Hf-182W isotope system to the146Sm-142Nd isotope system during early silicate differentiation events on Earth. In this context, we demonstrate that the lack of resolvable182W excesses in the Itsaq rocks, despite142Nd excesses compared to the modern accessible mantle, is more consistent with the view that the bulk Earth has a non-chondritic Sm/Nd. In the non-chondritic Sm/Nd Earth model, the182W-142Nd chronometry constrains the age of the source mantle depletion for the Itsaq samples to more than ∼ 40 Ma after the Solar System origin. Our results cannot confirm the previous report of182W anomalies in the Eoarchean Itsaq meta-sediments, which were interpreted as reflecting an impact-derived meteoritic component