Stille/Diels-Alder reaction sequences: diversity-oriented access to novel steroids
- Sunnemann, Hans Wolf
- Hofmeister, Anja
- Magull, Jörg
- Banwell, Martin
- de Meijere, Armin
Publication date
December 2015
DOI Publisher
American Chemical Society (ACS) ISSN
1523-7060 Journal
Organic Letters Citation count (estimate)
9Abstract
An efficient, diversity-oriented approach to novel steroid analogues possessing a C-5β configuration begins with the Stille cross-coupling of enantiomerically pure cycloalkenylstannane trans-2 and enol triflate 3. The resulting diene trans-4 engages in
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