Observation of standard stars is of crucial importance in stellar photometry. We have studied the standard transformation relations of the UBV RI CCD photometric system at the Maidanak Astronomical Observatory in Uzbekistan. All observations were made with the AZT-22 1.5m telescope, SITe 2k CCD or Fairchild 486 CCD, and standard Bessell UBV RI filters from 2003 August to 2007 September. We observed many standard stars around the celestial equator observed by SAAO astronomers. The atmospheric extinction coefficients, photometric zero points, and time variation of photometric zero points of each night were determined. Secondary extinction coefficients and photometric zero points were very stable, while primary extinction coefficients showed a...