Observation of a Tungsten Alkane σ-Complex Showing Selective Binding of Methyl Groups Using FTIR and NMR Spectroscopies

Monitoring the formation and reactivity of organometallic alkane and fluoroalkane complexes with silanes and xe using time-resolved X-ray absorption fine structure spectroscopy

Bartlett, Stuart A.
Besley, Nicholas A.
Dent, Andrew J.
Diaz-Moreno, Sofia
Evans, John
Hamilton, Michelle L.
Hanson-Heine, Magnus W.D.
Horvath, Raphael
Manici, Valentina
Sun, Xue Zhong
Towrie, Michael
Wu, Lingjun
Zhang, Xiaoyi
George, Michael W.

July 2019

Complexes with weakly coordinating ligands are often formed in chemical reactions and can play key r...

The chemistry of group 6 metal carbonyls with N-Donor ligands

Hegarty, Cormac

January 1989

The behaviour of the photochemically produced tungsten pentacarbonyl is investigated by laser flash ...

The functionalization of methane and other hydrocarbons mediated by organometallic nitrosyl complexes of tungsten

Baillie, Rhett A.

January 2016

The novel family of Cp*W(NO)(H)(η³-allyl) complexes has been synthesized and characterized. Upon the...

Observation of a Tungsten Alkane σ-Complex Showing Selective Binding of Methyl Groups Using FTIR and NMR Spectroscopies

Rowan D. Young (2080894)
Douglas J. Lawes (1574674)
Anthony F. Hill (1502473)
Graham E. Ball (787412)

May 2012

The alkane σ-complex (HEB)W(CO)2(pentane) (HEB = η6-hexaethylbenzene) is pro...

Alkane alpha-complex observation with NMR and IR spectroscopies and the synthesis of rare carbido, carbon monosulfide and carbon disulfide complexes

Young, Rowan Drury

November 2018

This work describes the generation and observation of alkane {u03C3}-complexes by IR and NMR spectro...

A systematic approach to the generation of long-lived metal alkane complexes: combined IR and NMR study of (Tp)Re(CO)2(cyclopentane)

Duckett, Simon B.
George, Michael W.
Jina, Omar S.
Matthews, Steven L.
Perutz, Robin N.
Sun, Xue-Zhong
Vuong, Khuong Q.

January 2009

Short wavelength photolysis of (Tp)Re(CO)3 (Tp = tris(pyrazol-1-yl)borate) at low-temperature in cyc...

Monitoring reactive organic intermediates and short-lived organometallic species via NMR spectroscopy

Xu, Ran, Chemistry, Faculty of Science, UNSW

January 2014

Short-lived organic and organometallic species produced photochemically using a UV laser or UV lamp ...

Coordinatively unsaturated alkyne complexes of tungsten: synthesis and dynamic nuclear magnetic resonance studies of some but-2-yne derivatives

Davidson Jack L
Vasapollo Guiseppe

January 1988

Reaction of [{W(μ-Br)Br(CO)(MeC≡CMe)2}2] (I) with one molar equiv of Na(S2CNMe2), Na(S2PMe2), or Tl(...

Pathways to more stable neutral and cationic alkane sigma complexes

Holt, Camille, Chemistry, Faculty of Science, UNSW

January 2013

The work presented in this thesis details NMR spectroscopic studies undertaken at low temperatures a...

INFRARED SPECTRUM OF MATRIX-ISOLATED METHYLHYDROXYCARBENE

Baumann, C. A.

January 2007

Author Institution: Department of Chemistry, The University of Scranton, Scranton, PA 18510-4626The...

HINDERED LIGAND MOVEMENTS IN TRANSITION-METAL COMPLEXES DECARBONYL (ETA-4-DIENE) TUNGSTEN(0)

Özkar, Saim
KAYRAN, C
KREITER, CG

August 1992

1,2-Bis(dimethylphosphino)ethane-dicarbonyl-eta-4-diene-tungsten(0) complexes (diene = 1,3-butadiene...

183W NMR Spectroscopy Guides the Search for Tungsten Alkylidyne Catalysts for Alkyne Metathesis

Hillenbrand, J.
Leutzsch, M.
Gordon, C.
Copéret, C.
Fürstner, A.

November 2020

Triarylsilanolates are privileged ancillary ligands for molybdenum alkylidyne catalysts for alkyne m...

Pentakarbonilakriloilferrosenetungsten(0)'in sentezi ve tanımlanması

Boğa, Dilek Ayşe

January 2006

Pentacarbonylacryloylferrocenetungsten(0) complex was synthesized photochemically from hexacarbonylt...

ROTATIONAL SPECTRA OF CYCLOPENTADIENYLTUNGSTEN TRICARBONYL HYDRIDE COMPLEX USING PULSE BEAM FOURIER TRANSFORM MICROWAVE $SPECTROMETER^{a}$

Tanjaroon, Chakree
Karunatilaka, Chandana
Keck, Kristen
Kukolich, Stephen G.

January 2003

$^{a}$Supported by THE NATIONAL SCIENCE FOUNDATIONAuthor Institution: Department of Chemistry, Unive...

The Effect Of Tungsten(0)Pentacarbonyl On Coordinated Ligands

Byington, Janice Imada

January 1982

A series of monosubstituted tungsten(0)pentacarbonyl complexes, W(CO)5L (L = water, hydrogen sulfide...

Monitoring the formation and reactivity of organometallic alkane and fluoroalkane complexes with silanes and xe using time-resolved X-ray absorption fine structure spectroscopy

Bartlett, Stuart A.
Besley, Nicholas A.
Dent, Andrew J.
Diaz-Moreno, Sofia
Evans, John
Hamilton, Michelle L.
Hanson-Heine, Magnus W.D.
Horvath, Raphael
Manici, Valentina
Sun, Xue Zhong
Towrie, Michael
Wu, Lingjun
Zhang, Xiaoyi
George, Michael W.

July 2019

Complexes with weakly coordinating ligands are often formed in chemical reactions and can play key r...

The chemistry of group 6 metal carbonyls with N-Donor ligands

Hegarty, Cormac

January 1989

The behaviour of the photochemically produced tungsten pentacarbonyl is investigated by laser flash ...

The functionalization of methane and other hydrocarbons mediated by organometallic nitrosyl complexes of tungsten

Baillie, Rhett A.

January 2016

The novel family of Cp*W(NO)(H)(η³-allyl) complexes has been synthesized and characterized. Upon the...

Observation of a Tungsten Alkane σ-Complex Showing Selective Binding of Methyl Groups Using FTIR and NMR Spectroscopies

Rowan D. Young (2080894)
Douglas J. Lawes (1574674)
Anthony F. Hill (1502473)
Graham E. Ball (787412)

May 2012

The alkane σ-complex (HEB)W(CO)2(pentane) (HEB = η6-hexaethylbenzene) is pro...

Alkane alpha-complex observation with NMR and IR spectroscopies and the synthesis of rare carbido, carbon monosulfide and carbon disulfide complexes

Young, Rowan Drury

November 2018

This work describes the generation and observation of alkane {u03C3}-complexes by IR and NMR spectro...

A systematic approach to the generation of long-lived metal alkane complexes: combined IR and NMR study of (Tp)Re(CO)2(cyclopentane)

Duckett, Simon B.
George, Michael W.
Jina, Omar S.
Matthews, Steven L.
Perutz, Robin N.
Sun, Xue-Zhong
Vuong, Khuong Q.

January 2009

Short wavelength photolysis of (Tp)Re(CO)3 (Tp = tris(pyrazol-1-yl)borate) at low-temperature in cyc...

Monitoring reactive organic intermediates and short-lived organometallic species via NMR spectroscopy

Xu, Ran, Chemistry, Faculty of Science, UNSW

January 2014

Short-lived organic and organometallic species produced photochemically using a UV laser or UV lamp ...

Coordinatively unsaturated alkyne complexes of tungsten: synthesis and dynamic nuclear magnetic resonance studies of some but-2-yne derivatives

Davidson Jack L
Vasapollo Guiseppe

January 1988

Reaction of [{W(μ-Br)Br(CO)(MeC≡CMe)2}2] (I) with one molar equiv of Na(S2CNMe2), Na(S2PMe2), or Tl(...

Pathways to more stable neutral and cationic alkane sigma complexes

Holt, Camille, Chemistry, Faculty of Science, UNSW

January 2013

The work presented in this thesis details NMR spectroscopic studies undertaken at low temperatures a...

INFRARED SPECTRUM OF MATRIX-ISOLATED METHYLHYDROXYCARBENE

Baumann, C. A.

January 2007

Author Institution: Department of Chemistry, The University of Scranton, Scranton, PA 18510-4626The...

HINDERED LIGAND MOVEMENTS IN TRANSITION-METAL COMPLEXES DECARBONYL (ETA-4-DIENE) TUNGSTEN(0)

Özkar, Saim
KAYRAN, C
KREITER, CG

August 1992

1,2-Bis(dimethylphosphino)ethane-dicarbonyl-eta-4-diene-tungsten(0) complexes (diene = 1,3-butadiene...

183W NMR Spectroscopy Guides the Search for Tungsten Alkylidyne Catalysts for Alkyne Metathesis

Hillenbrand, J.
Leutzsch, M.
Gordon, C.
Copéret, C.
Fürstner, A.

November 2020

Triarylsilanolates are privileged ancillary ligands for molybdenum alkylidyne catalysts for alkyne m...

Pentakarbonilakriloilferrosenetungsten(0)'in sentezi ve tanımlanması

Boğa, Dilek Ayşe

January 2006

Pentacarbonylacryloylferrocenetungsten(0) complex was synthesized photochemically from hexacarbonylt...

ROTATIONAL SPECTRA OF CYCLOPENTADIENYLTUNGSTEN TRICARBONYL HYDRIDE COMPLEX USING PULSE BEAM FOURIER TRANSFORM MICROWAVE $SPECTROMETER^{a}$

Tanjaroon, Chakree
Karunatilaka, Chandana
Keck, Kristen
Kukolich, Stephen G.

January 2003

$^{a}$Supported by THE NATIONAL SCIENCE FOUNDATIONAuthor Institution: Department of Chemistry, Unive...

The Effect Of Tungsten(0)Pentacarbonyl On Coordinated Ligands

Byington, Janice Imada

January 1982

A series of monosubstituted tungsten(0)pentacarbonyl complexes, W(CO)5L (L = water, hydrogen sulfide...

Monitoring the formation and reactivity of organometallic alkane and fluoroalkane complexes with silanes and xe using time-resolved X-ray absorption fine structure spectroscopy

Bartlett, Stuart A.
Besley, Nicholas A.
Dent, Andrew J.
Diaz-Moreno, Sofia
Evans, John
Hamilton, Michelle L.
Hanson-Heine, Magnus W.D.
Horvath, Raphael
Manici, Valentina
Sun, Xue Zhong
Towrie, Michael
Wu, Lingjun
Zhang, Xiaoyi
George, Michael W.

July 2019

Complexes with weakly coordinating ligands are often formed in chemical reactions and can play key r...

The chemistry of group 6 metal carbonyls with N-Donor ligands

Hegarty, Cormac

January 1989

The behaviour of the photochemically produced tungsten pentacarbonyl is investigated by laser flash ...

The functionalization of methane and other hydrocarbons mediated by organometallic nitrosyl complexes of tungsten

Baillie, Rhett A.

January 2016

The novel family of Cp*W(NO)(H)(η³-allyl) complexes has been synthesized and characterized. Upon the...

Observation of a Tungsten Alkane σ-Complex Showing Selective Binding of Methyl Groups Using FTIR and NMR Spectroscopies

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