Two polymorphs of bis(1,10-phenanthroline-[kappa]<sup>2</sup>N,N')copper(I) iodide

The title complex, [Cu(C12H8N2)2]I, (I), has been crystallized in two polymorphic forms, both containing four-coordinate copper. Both forms are orthorhombic, with form (Ia) crystallizing in the primitive space group Pban and form (Ib) in the c-centred space group Ccca. In (Ia), the complex cation and the I<sup>-</sup> anion both have 222 crystallographic symmetry, and in (Ib), the complex cation has approximate 222 symmetry, with the I<sup>-</sup> counter-ion distributed over three special positions