Isolated supramolecules on surfaces studied with scanning tunneling microscopy

To date, supramolecular chemistry is an ever growing research field owing to its crucial role in molecular catalysis, recognition, medicine, data storage and processing as well as artificial photosynthetic devices. Different isolated supramolecules were prepared by molecular self-assembly on surfaces. This review mainly focuses on supramolecular aggregations on noble metal surfaces studied by scanning tunneling microscopy, including dimers, trimers, tetramers, pentamers, wire-like assemblies and Sierpinski triangular fractals. The variety of self-assembled structures reflects the subtle balance between intermolecular and molecule-substrate interactions, which to some extent may be controlled by molecules, substrates and the molecular coverage. The comparative study of different architectures helps identifying the operative mechanisms that lead to the structural motifs. The application of these mechanisms may lead to novel assemblies with tailored physicochemical properties. (C) 2016 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.National Natural Science Foundation of China [21522301, 21373020, 21403008, 61321001, 21433011, 61271050]; Ministry of Science and Technology [2014CB239302, 2013CB933404]; Research Fund for the Doctoral Program of Higher Education [20130001110029]; Deutsche Forschungsgemeinschaft (DFG) [SFB 677]SCI(E)中国科技核心期刊(ISTIC)中国科学引文数据库(CSCD)REVIEWzyshen@pku.edu.cn; yongfengwang@pku.edu.cn6807-8122