Efficient Defect Engineering for Solution Combustion Processed In-Zn-O thin films for high performance transistors

The oxygen related defects in the solution combustion-processed InZnO vitally affect the field-effect mobility and on-off characteristics in thin film transistors (TFTs). We use photoelectron spectroscopy to reveal that these defects can be well controlled by adjusting the atmosphere and flow rate during the combustion reaction, but are hardly affected by further post-annealing after the reaction. In device performance, the threshold voltage of the InZnO-TFTs was regulated in a wide range from 3.5 V to 11.0 V. To compromise the high field-effect mobility and good subthreshold properties, we fabricate the TFTs with double active layers of InZnO to achieve vertical gradience in defect distribution. The resulting TFT exhibits much higher field-effect mobility as 17.5 cm(2) . V-1. s(-1), a low reversed sub-threshold slope as 0.35 V/decade, and a high on-off ratio as 10(7). The presented understandings and methods on defect engineering are efficient in improving the device performance of TFTs made from the combustion reaction process.National Natural Science Foundations, China [51402366, 61404177, U1201254]; Science and Technology Planning Projects of Guangdong Province, China [2016B090918106, 2015B090924001, 2015B010132006]; Science and Technology Planning Project of Guangzhou, China [201607020036]; Guangdong Natural Science Funds [2016A030306046]SCI(E)ARTICLE93