Synthesis of Oligoparaphenylene-Derived Nanohoops Employing an Anthracene Photodimerization-Cycloreversion Strategy

Huang, Ze-Ao
Chen, Chen
Yang, Xiao-Di
Fan, Xiang-Bing
Zhou, Wen
Tung, Chen-Ho
Wu, Li-Zhu
Cong, Huan

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Publication date

January 2016

DOI

10.1021/jacs.6b07673

Publisher

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

ISSN

0002-7863

Journal

issn:0002-7863

Citation count (estimate)

Abstract

The century-old yet synthetically underexplored anthracene photodimerization cycloreversion reactions have been employed as the key steps to access highly strained aromatic hydrocarbons. Herein we report the chemical syntheses of oligoparaphenylene-derived nanohoops in five steps or less featuring a rigid dianthracene synthon. The newly synthesized nanohoops display intriguing experimental and computational properties.Thousand Youth Talents Plan; TIPC Director's Fund; NSFC [21672227]; CAS Strategic Priority Research Program [XDB17030200]SCI(E)EIPubMedARTICLEyangxiaodi@fudan.edu.cn; hcong@mail.ipc.ac.cn3511144-1114713

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Synthesis of Oligoparaphenylene-Derived Nanohoops Employing an Anthracene Photodimerization-Cycloreversion Strategy

Abstract

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Synthesis of Oligoparaphenylene-Derived Nanohoops Employing an Anthracene Photodimerization-Cycloreversion Strategy

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