ELECTROREDUCTION OF SOCl_2 ON GLASSY CARBON INFLUENCED BY THE PRESENCE OF WATER

The electroreduction of SOCl_2 in Li/LiAlCl_4-SOCl_2/porous carbon cell is generally accepted as following the reaction: 4Li+ 2SOCl_2 + 4e~-→2S + 2SO_2+4LiCl The solid reaction products LiCl and S cause passivation of the porous carton electrode and consequenyly limits its capacity.But the detail...The electroreduction of SOCl_2 in Li/LiAlCl_4-SOCl_2/porous carbon cell is generally accepted as following the reaction: 4Li+ 2SOCl_2 + 4e~-→2S + 2SO_2+4LiCl The solid reaction products LiCl and S cause passivation of the porous carton electrode and consequenyly limits its capacity.But the detail...Chinese Institute of Electronics、IEEE Beijing Section