Add to ORKGMetal-catalyzed hydroboration of alkynes usually proceed in a cis-addition manner.Applications of trans-hydroboration of terminal alkynes via a vinylidene intermediate are limited.trans-hydroboration of internal alkynes were first achieved by using[Cp*Ru(Me CN)3]PF6,as a catalyst1.DFT studies have b...中国化学会
Insights into the mechanism of the unusual trans-hydrogenation of internal alkynes catalyzed by {Cp*...
The purpose of the thesis is the catalyzed functionalization of alkynes, alkenes and arenes via hydr...
Violate the rule: The reigning stereochemical principle of hydroboration is the suprafacial delivery...
Recently, the Furstner group reported the first general trans-hydroboration of internal alkynes by u...
[Cp*RuCl](4) (1) has previously been shown to be the precatalyst of choice for stereochemically unor...
In contrast to all other transition-metal-catalyzed hydrostannation reactions documented in the lite...
Violate the rule: The reigning stereochemical principle of hydroboration is the suprafacial delivery...
An overview on the mechanisms of the trans-selective hydrogenation and hydrometalation of alkynes us...
The nonclassical ruthenium hydride pincer complex [Ru(PNP)(H)<sub>2</sub>(H<sub>2</sub>)] <b>1</b>...
The classical repertoire of synthetic organic chemistry is short of methods that allow triple bonds ...
The classical repertoire of synthetic organic chemistry is short of methods that allow triple bonds ...
Reactions of internal alkynes with R<sub>3</sub>M–H (M = Si, Ge, Sn) follow an unconventional trans-...
Reactions of internal alkynes with R3M–H (M = Si, Ge, Sn) follow an unconventional trans-addition mo...
[Cp*RuCl]<sub>4</sub> (<b>1</b>) has previously been shown to be the precatalyst of choice for stere...
Insights into the mechanism of the unusual trans-hydrogenation of internal alkynes catalyzed by {Cp*...
Insights into the mechanism of the unusual trans-hydrogenation of internal alkynes catalyzed by {Cp*...
The purpose of the thesis is the catalyzed functionalization of alkynes, alkenes and arenes via hydr...
Violate the rule: The reigning stereochemical principle of hydroboration is the suprafacial delivery...
Recently, the Furstner group reported the first general trans-hydroboration of internal alkynes by u...
[Cp*RuCl](4) (1) has previously been shown to be the precatalyst of choice for stereochemically unor...
In contrast to all other transition-metal-catalyzed hydrostannation reactions documented in the lite...
Violate the rule: The reigning stereochemical principle of hydroboration is the suprafacial delivery...
An overview on the mechanisms of the trans-selective hydrogenation and hydrometalation of alkynes us...
The nonclassical ruthenium hydride pincer complex [Ru(PNP)(H)<sub>2</sub>(H<sub>2</sub>)] <b>1</b>...
The classical repertoire of synthetic organic chemistry is short of methods that allow triple bonds ...
The classical repertoire of synthetic organic chemistry is short of methods that allow triple bonds ...
Reactions of internal alkynes with R<sub>3</sub>M–H (M = Si, Ge, Sn) follow an unconventional trans-...
Reactions of internal alkynes with R3M–H (M = Si, Ge, Sn) follow an unconventional trans-addition mo...
[Cp*RuCl]<sub>4</sub> (<b>1</b>) has previously been shown to be the precatalyst of choice for stere...
Insights into the mechanism of the unusual trans-hydrogenation of internal alkynes catalyzed by {Cp*...
Insights into the mechanism of the unusual trans-hydrogenation of internal alkynes catalyzed by {Cp*...
The purpose of the thesis is the catalyzed functionalization of alkynes, alkenes and arenes via hydr...
Violate the rule: The reigning stereochemical principle of hydroboration is the suprafacial delivery...