High Performance Shape Memory Epoxy/Carbon Nanotube Nanocomposites

A series of shape memory nanocomposites based on diglycidyl ether of bisphenol A (DGEBA) E51/methylhexahydrophthalic anhydride (MHHPA)/multiwalled carbon nanotube (MWCNT) with various stoichiometric ratios (r(s)) of DGEBA/MHHPA from 0.5 to 1.2 and filler contents of 0.25 and 0.75 wt % are fabricated. Their morphology, curing kinetics, phase transition, mechanical properties, thermal conduction, and shape memory behaviors are systematically investigated. The prepared materials show a wide range of glass transition temperatures (Tg) of ca. 65-140 degrees C, high flexural modulus (E) at room temperature up to ca. 3.0 GPa, high maximum stress (sm) up to ca. 30 MPa, high strain at break (eb) above 10%, and a fast recovery of 32 s. The results indicate that a small amount of MWCNT fillers (0.75 wt %) can significantly increase all three key mechanical properties (E, sigma(m), and epsilon(b)) at temperatures close to Tg, the recovery rate, and the repetition stability of the shape memory cycles. All of these remarkable advantages make the materials good candidates for the applications in aerospace and other important fields.National Key Basic Research Program of China [2012CB937503, 2013CB934203]; National High Technology Research and Development Program of China [2013AA031803]; "Strategic Priority Research Program" of the Chinese Academy of Sciences [XDA09030200]; National Natural Science Foundation of China [11225210, 51571183]; Fundamental Research Funds for the Central UniversitiesSCI(E)EIARTICLEzhaoj@nanoctr.cn; yuxiang@cugb.edu.cn; zhong.zhang@nanoctr.cn1311-320