A palladium-catalyzed cross-coupling reaction of electron-deficient aryl fluorides with aryl N-tosylhydrazones has been reported. Mechanistically, this approach involves C-F bond activation and migratory insertion of palladium carbene as the two key steps.National Basic Research Program (973 Program) [2012CB821600]; Natural Science Foundation of China [21472004, 21332002]SCI(E)ARTICLEwangjb@pku.edu.cn6813321-133235
Benzylic fluorides are suitable substrates for Pd(0)-catalyzed Tsuji–Trost substitution using carbon...
A practical, palladium-catalyzed synthesis of aryl fluorides from arylboronic acid derivatives is pr...
A practical, palladium-catalyzed synthesis of aryl fluorides from arylboronic acid derivatives is pr...
In this review, we summarize our recent development of palladium(0)-catalyzed cross-coupling reactio...
Transition-metal-catalyzed carbene transformations and cross-couplings represent two major reaction ...
A selection of carbon-fluorine bond-forming reactions is presented with particular focus on transiti...
The installation of carbon–fluorine and carbon-trifluoromethyl bonds in organic compounds can have a...
Conspectus: Aromatic fluorides are prevalent in both agrochemical and pharmaceutical agents. However...
The Pd-catalyzed reaction of N-tosylhydrazones and arylboronic acids provides olefin derivatives. Th...
Direct and regioselective alkynylation of highly fluorinated nitrobenzene derivatives by palladium-c...
The palladium-catalyzed cross coupling of vinyl and aryl triflates with 2-furylzine chloride: an eff...
This Communication describes studies of Ph–RF (RF = CF3 or CF2CF3) coupling at Pd complexes of gener...
We report the synthesis of fluorinated anilines by palladium-catalyzed coupling of fluoroalkylamines...
A practical, palladium-catalyzed synthesis of aryl fluorides from arylboronic acid derivatives is pr...
Ni(PCy<sub>3</sub>)<sub>2</sub>Cl<sub>2</sub> was demonstrated to effectively catalyze cross-coupli...
Benzylic fluorides are suitable substrates for Pd(0)-catalyzed Tsuji–Trost substitution using carbon...
A practical, palladium-catalyzed synthesis of aryl fluorides from arylboronic acid derivatives is pr...
A practical, palladium-catalyzed synthesis of aryl fluorides from arylboronic acid derivatives is pr...
In this review, we summarize our recent development of palladium(0)-catalyzed cross-coupling reactio...
Transition-metal-catalyzed carbene transformations and cross-couplings represent two major reaction ...
A selection of carbon-fluorine bond-forming reactions is presented with particular focus on transiti...
The installation of carbon–fluorine and carbon-trifluoromethyl bonds in organic compounds can have a...
Conspectus: Aromatic fluorides are prevalent in both agrochemical and pharmaceutical agents. However...
The Pd-catalyzed reaction of N-tosylhydrazones and arylboronic acids provides olefin derivatives. Th...
Direct and regioselective alkynylation of highly fluorinated nitrobenzene derivatives by palladium-c...
The palladium-catalyzed cross coupling of vinyl and aryl triflates with 2-furylzine chloride: an eff...
This Communication describes studies of Ph–RF (RF = CF3 or CF2CF3) coupling at Pd complexes of gener...
We report the synthesis of fluorinated anilines by palladium-catalyzed coupling of fluoroalkylamines...
A practical, palladium-catalyzed synthesis of aryl fluorides from arylboronic acid derivatives is pr...
Ni(PCy<sub>3</sub>)<sub>2</sub>Cl<sub>2</sub> was demonstrated to effectively catalyze cross-coupli...
Benzylic fluorides are suitable substrates for Pd(0)-catalyzed Tsuji–Trost substitution using carbon...
A practical, palladium-catalyzed synthesis of aryl fluorides from arylboronic acid derivatives is pr...
A practical, palladium-catalyzed synthesis of aryl fluorides from arylboronic acid derivatives is pr...