Chiral Phonons at High-Symmetry Points in Monolayer Hexagonal Lattices

In monolayer hexagonal lattices, the intravalley and intervalley scattering of electrons can involve chiral phonons at Brillouin-zone center and corners, respectively. At these high-symmetry points, there is a threefold rotational symmetry endowing phonon eigenmodes with a quantized pseudoangular momentum, which includes orbital and spin parts. Conservation of pseudoangular momentum yields selection rules for intravalley and intervalley scattering of electrons by phonons. Concrete predictions of helicity-resolved optical phenomena are made on monolayer molybdenum disulfide. The chiral phonons at Brillouin-zone corners excited by polarized photons can be detected by a valley phonon Hall effect. The chiral phonons, together with phonon circular polarization, phonon pseudoangular momentum, selection rules, and valley phonon Hall effect will extend the basis for valley-based electronics and phononics applications in the future.DOE-DMSE [DE-FG03-02ER45958]; NBRPC [2012CB-921300]; NSFC [91121004, 11574154]; Welch Foundation [F-1255]SCI(E)EIARTICLE1111