Transport properties of hydrogen-helium mixtures at extreme density and temperature conditions

We perform a systematic study of hydrogen-helium mixtures using quantum molecular dynamics (QMD) with a focus on the equations of state and structural and transport properties such as electrical conductivity, diffusion, and viscosity at conditions of giant planet interiors of 0.2 similar to 2.3 g/cm(3) and 1000 similar to 80000 K for a typical helium mass fraction of 0.245. The H-He separation is found at low temperatures by analyzing the trajectories and pair distribution functions. We show that the diffusion coefficients exhibit transitions from kinetics- to potential-, and then to demixing-dominated regimes. In addition, we identify the discontinuity feature of optical absorption of a H-He mixture at low density and temperature conditions, which results from the change from an intraband to an interband transition. The Stokes-Einstein relation between the diffusion and viscosity coefficients is also discussed.NSFC [11205019, 11474034, 11275032]; Foundations for Development of Science and Technology of China Academy of Engineering Physics [2015B0102022]SCI(E)EIPubMedARTICLEzhang_ping@iapcm.ac.cn40431089