3-Allyl-6,8-dimethoxy-1-tetralone as the intermediate projected for a synthesis of hypocrellin was studied for its facile formation from 3-(3,5-dimethoxy-benzyl)-5-hexenoic acid and its Wacker oxidation, addition of bromine and of hydrogen chloride. It and the diketone obtained by its Wacker oxidation were shown not susceptible towards oxidation by selenium dioxide.EI02167-1713
The syntheses of the three selenenium cations 17–19 derived from N-[n-butyl-(3-nitrobenzylimino)]phe...
Reaction of 6-quinolinol with formaldehyde and sodium sulphite gives the bisquinolinol (1b). Similar...
Although the number of reported peroxide natural products with important biological properties conti...
3-(3,5-Dimethoxybenzyl)-5-hexenoic acid (13) could be cycloacylated by a variant consistion of treat...
7-Methoxy-3-methyl-I-tetralone has been synthesised, which on oxidation with selenium dioxide gives,...
Part 1. The structurally complex perylenequinones comprise a family of natural products that possess...
Two closely related routes to dimethyl 3,10-dihydro-2,11-di-hydroxy-4,6,7,9-tetramethoxy-3,10-dioxo-...
对拟议的竹红菌素合成的中间体3-烯丙基-6,8-二甲氧基四氢萘-1-酮的形成反应、Wacker氧化、溴化和氯化氢加成等反应进行了研究、对它及其氧化产物二酮的二氧化硒氧化反应也进行了探索.国家自然科学基...
The efforts described in this dissertation encompass the total synthesis and biological assessment o...
The oxidation of substituted phenols with phenyliodonium diacetate in methanol was found to afford 2...
Pyrroloquinone ring systems are important structural units present in many biologically active molec...
In continuation of the work described in previous parts, 5-methoxy-4-methykoumarin, 4 :6-dimethylco...
In the first part of this thesis an 8-step synthesis of (±)-4-demethylaristolone 16 is described. Th...
Hydroperoxyeiscosatetraenoic acids (HPETEs) are biologically important polyunsaturated hydroperoxide...
1. The action of selenious acid on 3-carene in ethanolic solution was studied. It results in the for...
The syntheses of the three selenenium cations 17–19 derived from N-[n-butyl-(3-nitrobenzylimino)]phe...
Reaction of 6-quinolinol with formaldehyde and sodium sulphite gives the bisquinolinol (1b). Similar...
Although the number of reported peroxide natural products with important biological properties conti...
3-(3,5-Dimethoxybenzyl)-5-hexenoic acid (13) could be cycloacylated by a variant consistion of treat...
7-Methoxy-3-methyl-I-tetralone has been synthesised, which on oxidation with selenium dioxide gives,...
Part 1. The structurally complex perylenequinones comprise a family of natural products that possess...
Two closely related routes to dimethyl 3,10-dihydro-2,11-di-hydroxy-4,6,7,9-tetramethoxy-3,10-dioxo-...
对拟议的竹红菌素合成的中间体3-烯丙基-6,8-二甲氧基四氢萘-1-酮的形成反应、Wacker氧化、溴化和氯化氢加成等反应进行了研究、对它及其氧化产物二酮的二氧化硒氧化反应也进行了探索.国家自然科学基...
The efforts described in this dissertation encompass the total synthesis and biological assessment o...
The oxidation of substituted phenols with phenyliodonium diacetate in methanol was found to afford 2...
Pyrroloquinone ring systems are important structural units present in many biologically active molec...
In continuation of the work described in previous parts, 5-methoxy-4-methykoumarin, 4 :6-dimethylco...
In the first part of this thesis an 8-step synthesis of (±)-4-demethylaristolone 16 is described. Th...
Hydroperoxyeiscosatetraenoic acids (HPETEs) are biologically important polyunsaturated hydroperoxide...
1. The action of selenious acid on 3-carene in ethanolic solution was studied. It results in the for...
The syntheses of the three selenenium cations 17–19 derived from N-[n-butyl-(3-nitrobenzylimino)]phe...
Reaction of 6-quinolinol with formaldehyde and sodium sulphite gives the bisquinolinol (1b). Similar...
Although the number of reported peroxide natural products with important biological properties conti...