Catalytic asymmetric S-H insertion of carbenoids generated from aryldiazoacetates has been investigated with a number of chiral Rh(II) and Cu(I) catalysts. 12 % - 23 % ee enantioselectivity were achieved with chiral Rh(II) catalysts.Chemistry, OrganicSCI(E)8ARTICLE84-9
A general access to chiral dihydroindole derivatives in high yields is achieved by C–H functionaliza...
Chiral square-planar Rh(I) complexes based on new C2-symmetric NHC ligands have been synthesized se...
ABSTRACT: The first asymmetric insertion reactions of donor−donor carbenoids, i.e., those with no pe...
Catalytic asymmetric [2,3] sigmatropic rearrangement of sulfur ylides generated from aryldiazoacetat...
International audienceChiral square-planar Rh(I) complexes based on new C2-symmetric NHC ligands hav...
International audienceChiral square-planar Rh(I) complexes based on new C2-symmetric NHC ligands hav...
Chapter One reviews the literature, discussing the application of metallocarbenoids in asymmetric sy...
Recent advance on asymmetric hydrogenation of aromatic carbocyclic rings and thiophenes has been des...
This thesis examines the understanding and development of Rh(I)-catalysed cross-couplings with arylb...
The first asymmetric insertion reactions of donor-donor carbenoids, i.e., those with no pendant elec...
Olefins undergo cyclopropanation with diphenylsulfonium (ethoxycarbonyl)methylide (=diphenylsulfoniu...
One of the most recent developments in asymmetric catalysis is to employ two or more catalysts under...
Rh-catalyzed asymmetric hydrogenation has emerged as a powerful tool for the manufacturing of chiral...
The first highly enantioselective S-H bond insertion reaction was developed by cooperative catalysis...
Donor/donor carbenes are relatively new in the field of carbene chemistry; although applications in ...
A general access to chiral dihydroindole derivatives in high yields is achieved by C–H functionaliza...
Chiral square-planar Rh(I) complexes based on new C2-symmetric NHC ligands have been synthesized se...
ABSTRACT: The first asymmetric insertion reactions of donor−donor carbenoids, i.e., those with no pe...
Catalytic asymmetric [2,3] sigmatropic rearrangement of sulfur ylides generated from aryldiazoacetat...
International audienceChiral square-planar Rh(I) complexes based on new C2-symmetric NHC ligands hav...
International audienceChiral square-planar Rh(I) complexes based on new C2-symmetric NHC ligands hav...
Chapter One reviews the literature, discussing the application of metallocarbenoids in asymmetric sy...
Recent advance on asymmetric hydrogenation of aromatic carbocyclic rings and thiophenes has been des...
This thesis examines the understanding and development of Rh(I)-catalysed cross-couplings with arylb...
The first asymmetric insertion reactions of donor-donor carbenoids, i.e., those with no pendant elec...
Olefins undergo cyclopropanation with diphenylsulfonium (ethoxycarbonyl)methylide (=diphenylsulfoniu...
One of the most recent developments in asymmetric catalysis is to employ two or more catalysts under...
Rh-catalyzed asymmetric hydrogenation has emerged as a powerful tool for the manufacturing of chiral...
The first highly enantioselective S-H bond insertion reaction was developed by cooperative catalysis...
Donor/donor carbenes are relatively new in the field of carbene chemistry; although applications in ...
A general access to chiral dihydroindole derivatives in high yields is achieved by C–H functionaliza...
Chiral square-planar Rh(I) complexes based on new C2-symmetric NHC ligands have been synthesized se...
ABSTRACT: The first asymmetric insertion reactions of donor−donor carbenoids, i.e., those with no pe...