Palladium-Catalyzed Intermolecular Domino Reaction of gem-Dibromoenynes with Anilines; A One-Pot Synthesis of Quinolines and Quinolinones

Meng, Tianhao
Zhang, Wen-Xiong
Zhang, Hui-Jun
Liang, Yun
Xi, Zhenfeng

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Publication date

January 2012

DOI

10.1055/s-0032-1316613

Publisher

synthesis stuttgart

ISSN

0039-7881

Journal

issn:0039-7881

Citation count (estimate)

Abstract

An efficient domino process involving palladium-catalyzed amination of an alkenyl bromide, 1,5-H transfer, annulation via 6-exo-dig electrophilic cyclization, and palladium-catalyzed etherification, is described. This reaction provides an efficient one-pot synthesis of multi-substituted quinolines and quinolinones from gem-dibromoenynes and anilines.Chemistry, OrganicSCI(E)3ARTICLE172754-27624

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Palladium-Catalyzed Intermolecular Domino Reaction of gem-Dibromoenynes with Anilines; A One-Pot Synthesis of Quinolines and Quinolinones

Abstract

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Palladium-Catalyzed Intermolecular Domino Reaction of gem-Dibromoenynes with Anilines; A One-Pot Synthesis of Quinolines and Quinolinones

Abstract

Extracted data

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