Highly stereoselective [2,3]-sigmatropic rearrangement of sulfur ylide generated through Cu(I) carbene and sulfides

Ma, M
Peng, LL
Li, CK
Zhang, X
Wang, JB

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Publication date

January 2005

DOI

10.1021/ja055021d

Publisher

journal of the american chemical society

ISSN

0002-7863

Journal

issn:0002-7863

Citation count (estimate)

Abstract

A highly stereoselective [2,3]-sigmatropic rearrangement of sulfur ylide generated through Cu(I) carbene and allyl and propargyl sulfides by a double asymmetric induction approach that combines a chiral camphor sultam auxiliary and Cu(I) catalyst with chiral or achiral diimine ligands has been developed.Chemistry, MultidisciplinarySCI(E)EIPubMed56ARTICLE4315016-1501712

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Highly stereoselective [2,3]-sigmatropic rearrangement of sulfur ylide generated through Cu(I) carbene and sulfides

Abstract

Extracted data

Highly stereoselective [2,3]-sigmatropic rearrangement of sulfur ylide generated through Cu(I) carbene and sulfides

Abstract

Extracted data

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