Equilibration of quantum chaotic systems

The quantum ergordic theorem for a large class of quantum systems was proved by von Neumann [Z. Phys. 57, 30 (1929)] and again by Reimann [Phys. Rev. Lett. 101, 190403 (2008)] in a more practical and well-defined form. However, it is not clear whether the theorem applies to quantum chaotic systems. With a rigorous proof still elusive, we illustrate and verify this theorem for quantum chaotic systems with examples. Our numerical results show that a quantum chaotic system with an initial low-entropy state will dynamically relax to a high-entropy state and reach equilibrium. The quantum equilibrium state reached after dynamical relaxation bears a remarkable resemblance to the classical microcanonical ensemble. However, the fluctuations around equilibrium are distinct: The quantum fluctuations are exponential while the classical fluctuations are Gaussian.SCI(E)EIPubMed360621478