THE ADSORPTION PROPERTIES OF THE SILANIZED ACTIVE-CARBON

The adsorption isotherms of benzoic acid and benzaldehyde from aqueous solution onto the silanized active carbon have been measured at 25-degrees-C and 35-degrees-C. The changes of standard free energy DELTAG-degrees, enthalpy DELTAH-degrees and entropy DELTAS-degrees in adsorption processes have been calculated from the Langmuir parameter. The experimental data have been treated with Hill-de Boer equation. The results show that, (1) with the lapse of the silanized time, the adsorption amounts (mol . m-2) of benzoic acid and benzaldehyde increase greatly; -DELTAG-degrees- , -DELTAH-degrees increase slightly, and DELTAS-degrees shows to be positive. (2) the interaction between adsorbed molecules is weak, and the interaction between adsorbed molecule and the surface of the active carbon increase with silanization. (3) the benzene ring of the benzoid compounds is adsorbed on the surface of the active carbon.Chemistry, MultidisciplinarySCI(E)中文核心期刊要目总览(PKU)中国科学引文数据库(CSCD)25427-4335