A novel catalyst for liquid phase hydrogenation of m-dinitrobenzene to m-phenylenediamine

  • Liu, YX
  • Wei, ZJ
  • Chen, JX
  • Zhang, JY
  • Li, XX
  • Wei, XH
Publication date
January 2005
Publisher
中国化学快报英文版
Journal
1001-8417

Abstract

A novel lanthana-promoted nickel catalyst supported on silica for the liquid phase hydrogenation of m-dinitrobenzene to m-phenylenediamine was prepared by an incipient wetness sequential impregnation method. It was found that Ni-La/SiO2 catalyst exhibited high activity and stability for m-dinitrobenzene hydrogenation. Over this catalyst, the conversion of m-dinitrobenzene and the yield of m-phenylenediamine were up to 97.1% and 93.5%, respectively, at 373 K and 2.6 MPa hydrogen pressure after reaction for 1 h.Chemistry, MultidisciplinarySCI(E)中国科技核心期刊(ISTIC)3ARTICLE4531-5331

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