Add to ORKGProgress in synthetic methodology for six-membered silacycles with one silicon atom in the ring is introduced. Six-membered silacycles are synthesized by the following methods: ring closure by silylation of alpha, omega-dimetallic compounds, [4+2] cycloaddition reaction involving silenes, ring closure by C-Si bond formation, ring closure by C-C bond formation, ring expansion reaction of smaller silacycles, etc. A variety of silacyclohexane, silacyclohexene and silacyclohexadiene derivatives are readily accessible by these transformations.. Further application of six-membered silacycles in organic chemistry and materials science can be envisioned.Chemistry, MultidisciplinarySCI(E)中文核心期刊要目总览(PKU)中国科技核心期刊(ISTIC)6ARTICLE7-81475-14862
Azhakar R, Roesky HW, Ghadwal R, Holstein JJ, Dittrich B. An access to base-stabilized three-membere...
International audienceDeveloping access to new heterocycles is a constant challenge in synthetic che...
Silenes generated through a silyl-modified Peterson olefination procedure can be trapped with a rang...
Six-membered silacycles are a class of important cyclic compounds in organosilicon chemistry, which ...
Four-membered silacycles are a class of important small cyclic compounds in organosilicon chemistry,...
Ziche W, Wolff A, Auner N, Sewald N. Silaheterocycles. 26. Facile Synthesis of Silicon Dichloro Subs...
L'INTRODUCTION D'UN ATOME DE SILICIUM A LA PLACE D'UN ATOME DE CARBONE DANS DES MOLECULES POLYCYCLIQ...
Stable 1-bromo-1-silacyclopropanes were synthesized in high yields from the reaction of the stable b...
Azhakar R, Ghadwal R, Roesky HW, et al. Reaction of N-Heterocyclic Silylenes with Thioketone: Format...
Although the use of silicon-based reagents has undergone rapid development during the last twenty ye...
Silenes, compounds containing a Si=c double bond, are highly reactive and are normally observed as t...
In an attempt to stabilize a silicon carbon (p-p)(pi) bond by incorporating it into a benzenoid fram...
A variety of silacycles including benzosiloles, six- and eight-membered silacyclic skeletons, were e...
A palladium-catalyzed hydroxycyclization reaction of 1,7-enynes to afford seven-membered silacycles ...
Im Rahmen der vorliegenden Arbeit wurden siliciumhaltige Derivate des allosteren Modulators W84 und ...
Azhakar R, Roesky HW, Ghadwal R, Holstein JJ, Dittrich B. An access to base-stabilized three-membere...
International audienceDeveloping access to new heterocycles is a constant challenge in synthetic che...
Silenes generated through a silyl-modified Peterson olefination procedure can be trapped with a rang...
Six-membered silacycles are a class of important cyclic compounds in organosilicon chemistry, which ...
Four-membered silacycles are a class of important small cyclic compounds in organosilicon chemistry,...
Ziche W, Wolff A, Auner N, Sewald N. Silaheterocycles. 26. Facile Synthesis of Silicon Dichloro Subs...
L'INTRODUCTION D'UN ATOME DE SILICIUM A LA PLACE D'UN ATOME DE CARBONE DANS DES MOLECULES POLYCYCLIQ...
Stable 1-bromo-1-silacyclopropanes were synthesized in high yields from the reaction of the stable b...
Azhakar R, Ghadwal R, Roesky HW, et al. Reaction of N-Heterocyclic Silylenes with Thioketone: Format...
Although the use of silicon-based reagents has undergone rapid development during the last twenty ye...
Silenes, compounds containing a Si=c double bond, are highly reactive and are normally observed as t...
In an attempt to stabilize a silicon carbon (p-p)(pi) bond by incorporating it into a benzenoid fram...
A variety of silacycles including benzosiloles, six- and eight-membered silacyclic skeletons, were e...
A palladium-catalyzed hydroxycyclization reaction of 1,7-enynes to afford seven-membered silacycles ...
Im Rahmen der vorliegenden Arbeit wurden siliciumhaltige Derivate des allosteren Modulators W84 und ...
Azhakar R, Roesky HW, Ghadwal R, Holstein JJ, Dittrich B. An access to base-stabilized three-membere...
International audienceDeveloping access to new heterocycles is a constant challenge in synthetic che...
Silenes generated through a silyl-modified Peterson olefination procedure can be trapped with a rang...