Synthesis, crystal structure, and properties of a binuclear copper(II) complex containing an oxalate bridge
- Bian, HD
- Tian, JL
- Liu, ZQ
- Gu, W
- Xu, JY
- Yan, SP
- Liao, DZ
- Jiang, ZH
- Cheng, P
Publication date
January 2004
DOI Publisher
zeitschrift fur anorganische und allgemeine chemie ISSN
0044-2313 Journal
issn:0044-2313 Citation count (estimate)
9Abstract
The complex [Cu-2(L)(2)(mu(2)-C2O4)].CH3OH (1) has been synthesized and characterized by IR, UV, ESR and variable temperature magnetic susceptibility measurement, where L = 1-(ethylamino)-2-(salicylideneamino)ethane. The crystal X-ray diffraction reveals that complex 1 has a mu(2)-C2O42- bridge. The complex exhibits ferromagnetic couplings between the copper atoms bridged by oxalate dianion, which is rare in oxalato-bridged copper complexes.http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000189145800026&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701Chemistry, Inorganic & NuclearSCI(E)7ARTICLE2327-33063
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