Synthesis, crystal structure and magnetic behavior of two cobalt coordination polymers with 1,2-bis(1,2,4-triazol-1-yl)ethane and dicyanamide

Li, Bao-Long
Wang, Xin-Yi
Zhu, Xia
Gao, Song
Zhang, Yong

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Publication date

January 2007

DOI

10.1016/j.poly.2007.07.044

Publisher

polyhedron

ISSN

0277-5387

Journal

0277-5387

Citation count (estimate)

Abstract

Two cobalt(II) coordination polymers formed from bte (bte = 1,2-bis(1,2,4-triazol-1-yl)ethane), namely [Co(bte)(2)(dca)(2)]n (1) and {[Co(bte)(dca)(2)]center dot H2O}n (2), have been synthesized and characterized by elementary analyses, IR, thermogravimetric analyses, X-ray diffraction analyses and magnetic measurements. Compound 1 is a double-chain with Co(II) centers bridged by bte, containing metallocycles of [Co-2(bte)(2)] and trans dca as termination ligands. In 2, each Co(II) center is bonded by two bridging bte ligands and four dca as mu-1,5-dca in different orientations in the 3D network. (C) 2007 Elsevier Ltd. All rights reserved.http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&K...

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Synthesis, crystal structure and magnetic behavior of two cobalt coordination polymers with 1,2-bis(1,2,4-triazol-1-yl)ethane and dicyanamide

Abstract

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Synthesis, crystal structure and magnetic behavior of two cobalt coordination polymers with 1,2-bis(1,2,4-triazol-1-yl)ethane and dicyanamide

Abstract

Extracted data

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