Acid-promoted reaction of sulfanyl group substituted allenic aldehyde with amine affords pyrrole derivatives in high yields. The neighboring group participation of the sulfanyl group is the driving force in this transformation.Chemistry, OrganicSCI(E)0ARTICLE81445-1448
The sulfonation reaction has been particularly useful to prepare amphiphilic derivatives of 5,10,15-...
The reaction of sulfonylpyrroles with nitroalkanes in the presence of KF/alumina generates 3-(2-nitr...
1-Sulfonyl-1,2,3-triazoles, readily prepared from terminal alkynes and sulfonyl azides, react with a...
Sulfenyl dipyrroles feature two pyrroles linked via a sulfenyl bridge. The synthesis of sulfenyl dip...
Pyrrolidines are widely prevalent in pharmaceuticals, catalysis and agrochemicals. The (3+2) cycload...
Tri-substituted pyrrole derivatives were successfully synthesized from aminoaldehyde and α-diazocarb...
N-[2-(Phenylsulfinylmethyl)phenyl]pyrrole (4) undergoes transfer sulfenylation to N-(2-chloromethylp...
The reaction of N-sulfonyl propargylamides in the presence of a base catalyst selectively affords 5-...
The conjugated bis(sulfonyl)nitrobutadienes 1 undergo, with primary amines, competitive MeSO2 replac...
Reaction of alpha-amido sulfones with nitro ketals promoted by KF on alumina provides the correspond...
2-Trifluoromethyl-5-(arylsulfonyl)methyl pyrroles and 2-trifluoromethyl-4-(arylsulfonyl) methyl pyrr...
Golden touch: Gold?catalyzed reaction of N?sulfonyl hydroxylamines with terminal alkyne led to 3?pyr...
A gold-catalyzed cascade reaction of conjugated diynamides has been developed. In this way, a series...
The development of new synthetic methods in organic chemistry is of importance because new routes to...
Pyrrole and its derivatives react smoothly with acid chlorides and sulfonyl chlorides in the presenc...
The sulfonation reaction has been particularly useful to prepare amphiphilic derivatives of 5,10,15-...
The reaction of sulfonylpyrroles with nitroalkanes in the presence of KF/alumina generates 3-(2-nitr...
1-Sulfonyl-1,2,3-triazoles, readily prepared from terminal alkynes and sulfonyl azides, react with a...
Sulfenyl dipyrroles feature two pyrroles linked via a sulfenyl bridge. The synthesis of sulfenyl dip...
Pyrrolidines are widely prevalent in pharmaceuticals, catalysis and agrochemicals. The (3+2) cycload...
Tri-substituted pyrrole derivatives were successfully synthesized from aminoaldehyde and α-diazocarb...
N-[2-(Phenylsulfinylmethyl)phenyl]pyrrole (4) undergoes transfer sulfenylation to N-(2-chloromethylp...
The reaction of N-sulfonyl propargylamides in the presence of a base catalyst selectively affords 5-...
The conjugated bis(sulfonyl)nitrobutadienes 1 undergo, with primary amines, competitive MeSO2 replac...
Reaction of alpha-amido sulfones with nitro ketals promoted by KF on alumina provides the correspond...
2-Trifluoromethyl-5-(arylsulfonyl)methyl pyrroles and 2-trifluoromethyl-4-(arylsulfonyl) methyl pyrr...
Golden touch: Gold?catalyzed reaction of N?sulfonyl hydroxylamines with terminal alkyne led to 3?pyr...
A gold-catalyzed cascade reaction of conjugated diynamides has been developed. In this way, a series...
The development of new synthetic methods in organic chemistry is of importance because new routes to...
Pyrrole and its derivatives react smoothly with acid chlorides and sulfonyl chlorides in the presenc...
The sulfonation reaction has been particularly useful to prepare amphiphilic derivatives of 5,10,15-...
The reaction of sulfonylpyrroles with nitroalkanes in the presence of KF/alumina generates 3-(2-nitr...
1-Sulfonyl-1,2,3-triazoles, readily prepared from terminal alkynes and sulfonyl azides, react with a...