A novel self-promoted Morita-Baylis-Hillman-like dimerization
- Li Qiang
- Wongkhan, Kittiya
- Luo XianCai
- Batsanov, Andrei S.
- Howard, Judith A. K.
- Lan Yu
- Wu YunDong
- Marder, Todd B.
- Lei Aiwen
Publication date
January 2010
DOI Publisher
科学通报 英文版 ISSN
1001-6538 Journal
issn:1001-6538 Citation count (estimate)
3Abstract
While stable in CH(2)Cl(2), hexane or THF, in the presence of MeOH, self-promoted dimerization of the triarylphosphine-alkene 1, a ligand for Pd-catalyzed reactions, produced an unusual racemic bis(phosphine) 2 in high yield. The reaction of 2 with Pd(dba)(2), followed by oxidative addition of p-IC(6)H(4)NO(2), yielded a trans-chelated Pd(II) aryl iodide complex.http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000281695100005&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701Multidisciplinary SciencesSCI(E)2ARTICLE252794-27985
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