Electrochemistry of M(eta(2)-C-60)(CO)(2)(phen)(dbm) (M = W 1, Mo 2; phen = 1,10-phenanthroline; dbm = dibutyl maleate) shows that the complexes undergo four sequential reduction processes. As with foe C-60, the first three electrons add reversibly (even if the relevant potentials are shifted ca. 0.15 V toward negative values), whereas the fourth reduction features chemical irreversibility. Cyclic voltammetry gives evidence that, as a consequence of the latter process, the metal fragment decomplexes and [C-60](3-) is released. In good agreement with this picture, a qualitative MO approach shows four close LUMOs for the ground state structure of the uncharged complexes. The first three levels are delocalized over C-60 (somewhat extended to t...
Our group has recently reported a monometallic Molybdenum complex supported by a terphenyl diphosphi...
The electrochemistry of a series of W(CO)4(LL) complexes, where LL is an aromatic α-diimine ligand, ...
The thermodynamics of fullerene C60 electroreduction, and 2′-ferrocenylpyrrolidino [3′,4′;1,2][C60]f...
The electrochemical behaviour of the series (C-60)[Mo(CO)(2)(phen)(dbm)](n) (n = 1-3) has been studi...
Electrochemical investigations on the dumb-bell like [Mo(η2-C60 )2 (CO)2 (dbc-bipy)] show that the t...
Chapter 1. The anodic electrochemistry of corannulene, cyclopentacorannulene, and compounds 10, 32, ...
The 18-electron cationic complexes [Mo(CO)3(η5-C5Me5)L]+[L = CO, p-MeC6H4NC, or P(OMe)3] undergo, in...
Electrochemical behavior of mono- and bimetallic chromiumtricarbonyl and cationic manganesetricarbon...
Systematic electrochemical studies have been carried out on a series of covalent fullerene C<sub>60<...
Thermal substitution reaction of Cr(CO)4(η2:2-1,5-cyclooctadiene), Mo(CO)4(η2:2-norbornadiene), and ...
International audienceThe electrochemical reduction of [Mo2Cp2(CO)4_μ-η2:η 3-HC≡C-C(R1)(R2)_]+ compl...
Pure endohedral metallofullerenes Sm@C-82 and Gd@C-82 have been separated by HPLC and their cage sym...
富勒烯(C60)的钼配合物Mo(η\+2-C60)(CO)2(phen)(dbm)(phen=1,10-phenanthroline,dbm=dibutyl maleate)的晶体结构在低温下被测定....
The electrochemistry and spectroelectrochemistry of [Cl2FeS2MS2FeCl2]n- clusters (where n = 2 for M ...
Novel covalently linked parachute-shape C60-porphyrin dyads show appreciable electronic interactio...
Our group has recently reported a monometallic Molybdenum complex supported by a terphenyl diphosphi...
The electrochemistry of a series of W(CO)4(LL) complexes, where LL is an aromatic α-diimine ligand, ...
The thermodynamics of fullerene C60 electroreduction, and 2′-ferrocenylpyrrolidino [3′,4′;1,2][C60]f...
The electrochemical behaviour of the series (C-60)[Mo(CO)(2)(phen)(dbm)](n) (n = 1-3) has been studi...
Electrochemical investigations on the dumb-bell like [Mo(η2-C60 )2 (CO)2 (dbc-bipy)] show that the t...
Chapter 1. The anodic electrochemistry of corannulene, cyclopentacorannulene, and compounds 10, 32, ...
The 18-electron cationic complexes [Mo(CO)3(η5-C5Me5)L]+[L = CO, p-MeC6H4NC, or P(OMe)3] undergo, in...
Electrochemical behavior of mono- and bimetallic chromiumtricarbonyl and cationic manganesetricarbon...
Systematic electrochemical studies have been carried out on a series of covalent fullerene C<sub>60<...
Thermal substitution reaction of Cr(CO)4(η2:2-1,5-cyclooctadiene), Mo(CO)4(η2:2-norbornadiene), and ...
International audienceThe electrochemical reduction of [Mo2Cp2(CO)4_μ-η2:η 3-HC≡C-C(R1)(R2)_]+ compl...
Pure endohedral metallofullerenes Sm@C-82 and Gd@C-82 have been separated by HPLC and their cage sym...
富勒烯(C60)的钼配合物Mo(η\+2-C60)(CO)2(phen)(dbm)(phen=1,10-phenanthroline,dbm=dibutyl maleate)的晶体结构在低温下被测定....
The electrochemistry and spectroelectrochemistry of [Cl2FeS2MS2FeCl2]n- clusters (where n = 2 for M ...
Novel covalently linked parachute-shape C60-porphyrin dyads show appreciable electronic interactio...
Our group has recently reported a monometallic Molybdenum complex supported by a terphenyl diphosphi...
The electrochemistry of a series of W(CO)4(LL) complexes, where LL is an aromatic α-diimine ligand, ...
The thermodynamics of fullerene C60 electroreduction, and 2′-ferrocenylpyrrolidino [3′,4′;1,2][C60]f...