Synthesis, characterization and crystal structure of some organotinferrocene and organoarsinoferrocene derivatives

N ,N -二甲基氨甲基二茂铁的单锂化物与三苄基氯化锡反应 ,得到 1 -二甲氨甲基 -2 -三苄基锡二茂铁( ) ;与二苄基二氯化锡反应 ,得到二苄基二 [2 -(二甲氨甲基 )二茂铁基 ]锡 ( ) .1 -二甲氨甲基 -2 -(二苯胂基 )二茂铁经单锂化后 ,再与二苯基氯化胂反应 ,生成 1 -二甲氨甲基 -2 ,5 -二 (二苯胂基 )二茂铁 ( ) ;在四甲基乙二胺存在下 ,1 -二甲氨甲基 -2 -(二苯胂基 )二茂铁经双锂化后 ,再与二苯基氯化胂反应 ,得到 1 -二甲氨甲基 -2 ,5 ,1′-三 (二苯胂基 )二茂铁 ( ) .化合物 — 经元素分析和 1 H N...The monolithio compound of N, N-dimethylaminomethylferrocene reacted with tribenzyltin chloride and dibenzyldichlorotin to form 2-(tribenzyltin)dimethylaminomethylferrocene(I) and dibenzyl bis (2-dimethylaminomethylferrocenyl) tin (II) respectively. While the monolithio compound of 2(diphenylarsino)dimethylaminomethylferrocene reacted with diphenylchloroarsine to give 2,5-di(diphenylarsino)dimethylaminomethylferrocene(II). The reaction of the dilithio compound of 2-(diphenylarsino) dimethylaminomethylferrocene with 2 mol diphenylchloroarsine gave 2, 5,1' -tri(diphenylarsino)dimethylaminomethylferrocene (IV). The structures of the products were characterized by elemental analysis and H-1 NMR spectra. The structure of compound IV was established by X-ray crystal structure determination. The crystal of N is triclinic, space group P (1) over bar, with unit cell parameters: a = 1.054 8(2) nm, b = 1.362 2(3) nm, c=1.584 6(3) nm, a=95.87(3)degrees, beta =96.54(3)degrees, gamma =107.67(3)degrees, Z=2.http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000172215200014&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701SCI(E)中文核心期刊要目总览(PKU)中国科学引文数据库(CSCD)1091496-15002