Palladium(0)-Catalyzed Cross-Coupling of 1,1-Diboronates with Vinyl Bromides and 1,1-Dibromoalkenes

Li, Huan
Zhang, Zhikun
Shangguan, Xianghang
Huang, Shan
Chen, Jun
Zhang, Yan
Wang, Jianbo

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Publication date

January 2014

DOI

10.1002/anie.201407000

Publisher

angewandte chemie international edition

ISSN

1433-7851

Journal

1521-3773

Citation count (estimate)

Abstract

Palladium-catalyzed cross-coupling reactions of 1,1-diboronates with vinyl bromides and dibromoalkenes were found to afford 1,4-dienes and allenes, respectively. These reactions utilize the high reactivities of both 1,1-diboronates and allylboron intermediates generated in the initial coupling.http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000344050700038&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701Chemistry, MultidisciplinarySCI(E)PubMed15ARTICLEwangjb@pku.edu.cn4411921-119255

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Palladium(0)-Catalyzed Cross-Coupling of 1,1-Diboronates with Vinyl Bromides and 1,1-Dibromoalkenes

Abstract

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Palladium(0)-Catalyzed Cross-Coupling of 1,1-Diboronates with Vinyl Bromides and 1,1-Dibromoalkenes

Abstract

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