2-Deoxyglycosides were synthesized in high alpha-selectivity by the direct addition of alcohols to D-glucal and D-galactal catalyzed by TMSI and PPh3. The acid labile isopropylidene group is tolerated under this condition. (C) 2012 Elsevier Ltd. All rights reserved.http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000307823200003&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701Biochemistry & Molecular BiologyChemistry, AppliedChemistry, OrganicSCI(E)EIPubMed6ARTICLE19-2235
Natural products are a vital resource to humanity. Natural products play a role in almost half of th...
Alkyl glycosides were synthesised from starch and alcohols using Aspergillus oryzae a-amylase as cat...
Chapter 1 introduces that glycals as one type of unsaturated carbohydrates specialized with a double...
International audienceEnzyme-catalyzed preparation ofp-2_deo~-D-glucosides ami galaccosides includin...
B(C6F5)3 enables the metal-free unprecedented substrate-controlled direct α-stereoselective synthesi...
The glycosylation of alcohols by the new 2-O-MEM-substituted d-galactal-derived allyl epoxide afford...
Palladium (II) in combination with a monodentate phosphine ligand enables the unprecedented direct a...
The stereocontrolled synthesis of 2-deoxy-d-<i>arabino</i>-hexopyranosides (“galactopyranosides”) us...
The thio-additions of glycals were efficiently promoted by a stoichiometric amount of trimethylsilyl...
217 p.Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2003.New methods for the synthesis...
Control of glycoside bond stereochemistry is the central challenge in the synthesis of oligosacchari...
alpha-Galactosyl ceramide is synthesized from D-lyxose in 32% overall yield in five steps. The short...
Due to the character of the original source materials and the nature of batch digitization, quality ...
2-Deoxy- and 2,6-dideoxyglycosyl trichloroacetimidates, phosphites and fluorides are efficiently act...
Lewis acid mediated stereoselective synthesis of 2-deoxy-O-glycosides has been demonstrated using 2-...
Natural products are a vital resource to humanity. Natural products play a role in almost half of th...
Alkyl glycosides were synthesised from starch and alcohols using Aspergillus oryzae a-amylase as cat...
Chapter 1 introduces that glycals as one type of unsaturated carbohydrates specialized with a double...
International audienceEnzyme-catalyzed preparation ofp-2_deo~-D-glucosides ami galaccosides includin...
B(C6F5)3 enables the metal-free unprecedented substrate-controlled direct α-stereoselective synthesi...
The glycosylation of alcohols by the new 2-O-MEM-substituted d-galactal-derived allyl epoxide afford...
Palladium (II) in combination with a monodentate phosphine ligand enables the unprecedented direct a...
The stereocontrolled synthesis of 2-deoxy-d-<i>arabino</i>-hexopyranosides (“galactopyranosides”) us...
The thio-additions of glycals were efficiently promoted by a stoichiometric amount of trimethylsilyl...
217 p.Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2003.New methods for the synthesis...
Control of glycoside bond stereochemistry is the central challenge in the synthesis of oligosacchari...
alpha-Galactosyl ceramide is synthesized from D-lyxose in 32% overall yield in five steps. The short...
Due to the character of the original source materials and the nature of batch digitization, quality ...
2-Deoxy- and 2,6-dideoxyglycosyl trichloroacetimidates, phosphites and fluorides are efficiently act...
Lewis acid mediated stereoselective synthesis of 2-deoxy-O-glycosides has been demonstrated using 2-...
Natural products are a vital resource to humanity. Natural products play a role in almost half of th...
Alkyl glycosides were synthesised from starch and alcohols using Aspergillus oryzae a-amylase as cat...
Chapter 1 introduces that glycals as one type of unsaturated carbohydrates specialized with a double...