Preparation of fullerenol, fullerenone, and aminofullerene derivatives through selective cleavage of fullerene C-H, C-C, C-N, and C-O bonds in fullerene-mixed peroxide derivatives

Jiang, Zhongping
Zhang, Yan
Gan, Liangbing
Wang, Zheming

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Publication date

January 2008

DOI

10.1016/j.tet.2008.08.053

Publisher

tetrahedron

ISSN

0040-4020

Journal

issn:0040-4020

Citation count (estimate)

Abstract

Various reactions of fullerene-mixed peroxides were investigated in an effort to explore the chemistry of functional groups On the fullerene surface. Amines convert fullerene peroxides into fullerene epoxides through S(N)2' type reaction. Lewis acid catalyzed hydrolysis of fullerene epoxides led to vicinal fullerendiols, which may be oxidized into fullerendiones by diacetoxyiodobenzene (DIB). Alcohols and amines react with the adjacent dione to form acetal or hemiacetal groups through different mechanisms. (C) 2008 Elsevier Ltd. All rights reserved.http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000261284600006&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b1...

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Preparation of fullerenol, fullerenone, and aminofullerene derivatives through selective cleavage of fullerene C-H, C-C, C-N, and C-O bonds in fullerene-mixed peroxide derivatives

Abstract

Extracted data

Preparation of fullerenol, fullerenone, and aminofullerene derivatives through selective cleavage of fullerene C-H, C-C, C-N, and C-O bonds in fullerene-mixed peroxide derivatives

Abstract

Extracted data

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