A novel lysine bearing vinyl monomer, (S)-2-(tert-butoxycarbonylamino)-6-(4'-vinylbenzamido)hexanoic acid, was designed and synthesized. It underwent reversible addition fragmentation chain transfer polymerization induced by azobisisobutyronitrile in the presence of 2-cyano-2-propyl dodecyl trithiocarbonate in dioxane at 65 degrees C. The number-average molecular weights of the resultant polymers increased linearly with the monomer conversion and the molecular weight distribution indices kept relatively low, indicating a well-controlled chain growth process. After deprotection of N-Boc groups, the monomer and the polymers were used as stereospecific inhibitors in the fractional crystallization of racemic glutamic acid monohydrochloride...
A synthetic strategy has been developed for the preparation of immobilized 1,2-aminoalcohols startin...
Despite significant advances in organocatalysis, stereoselective polymerization reactions utilizing ...
Chiral polymeric Co(III) salen complexes with chiral ((<i>R</i>)/(<i>S</i>)-BINOL, diethyl tartrate...
Control of stereoregularity is inherent to precision polymerization chemistry for the development of...
Chiral molecules are versatile building blocks for the synthesis of pharmaceuticals and fine chemica...
Abstract: A new strategy for the synthesis of chiral monomers for co-polymerization with styrene is ...
Synthetic polynucleotide analogs were prepared by grafting nucleic acid base derivatives onto hydrop...
Leucine/isoleucine side chain polymers are of interest due to their hydrophobicity and reported role...
The work presented in this thesis is aimed to design efficient reactive crystallization operations t...
Racemic AB monomers encompassing a secondary hydroxy group and a methyl ester moiety were synthesize...
Organocatalysis is becoming an important tool in polymer science because of its versatility and spec...
The enantioselective polymerization of methyl-substituted -caprolactones using Novozym 435 as the ca...
The production of enantiopure substances has drawn a lot of interest during the last decades. Especi...
Olefin polymerization is an extremely important industrial application of catalysis. A polymer's pro...
Materials with selective bio-responsiveness could have potential in medical applications. Here we re...
A synthetic strategy has been developed for the preparation of immobilized 1,2-aminoalcohols startin...
Despite significant advances in organocatalysis, stereoselective polymerization reactions utilizing ...
Chiral polymeric Co(III) salen complexes with chiral ((<i>R</i>)/(<i>S</i>)-BINOL, diethyl tartrate...
Control of stereoregularity is inherent to precision polymerization chemistry for the development of...
Chiral molecules are versatile building blocks for the synthesis of pharmaceuticals and fine chemica...
Abstract: A new strategy for the synthesis of chiral monomers for co-polymerization with styrene is ...
Synthetic polynucleotide analogs were prepared by grafting nucleic acid base derivatives onto hydrop...
Leucine/isoleucine side chain polymers are of interest due to their hydrophobicity and reported role...
The work presented in this thesis is aimed to design efficient reactive crystallization operations t...
Racemic AB monomers encompassing a secondary hydroxy group and a methyl ester moiety were synthesize...
Organocatalysis is becoming an important tool in polymer science because of its versatility and spec...
The enantioselective polymerization of methyl-substituted -caprolactones using Novozym 435 as the ca...
The production of enantiopure substances has drawn a lot of interest during the last decades. Especi...
Olefin polymerization is an extremely important industrial application of catalysis. A polymer's pro...
Materials with selective bio-responsiveness could have potential in medical applications. Here we re...
A synthetic strategy has been developed for the preparation of immobilized 1,2-aminoalcohols startin...
Despite significant advances in organocatalysis, stereoselective polymerization reactions utilizing ...
Chiral polymeric Co(III) salen complexes with chiral ((<i>R</i>)/(<i>S</i>)-BINOL, diethyl tartrate...