Sm@C-2v(3)-C-80: site-hopping motion of endohedral Sm atom and metal-induced effect on redox profile

Xu, Wei
Niu, Ben
Shi, Zujin
Lian, Yongfu
Feng, Lai

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Publication date

January 2012

DOI

10.1039/c2nr32193a

Publisher

nanoscale

ISSN

2040-3364

Journal

issn:2040-3364

Abstract

A new metallofullerene Sm@C-2v(3)-C-80 was synthesized and characterized. X-Ray analysis showed that the endohedral Sm atom undergoes a hopping motion between several off-center sites, even at low temperature. In addition, a comparative electrochemical study between Sm@C-2v(3)-C-80 and Yb@C-2v(3)-C-80 revealed their different redox potentials, suggesting a metal-induced effect on their redox profiles.http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000310940500031&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701Chemistry, MultidisciplinaryNanoscience & NanotechnologyMaterials Science, MultidisciplinaryPhysics, AppliedSCI(E)EIPubMed6AR...

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Sm@C-2v(3)-C-80: site-hopping motion of endohedral Sm atom and metal-induced effect on redox profile

Abstract

Extracted data

Sm@C-2v(3)-C-80: site-hopping motion of endohedral Sm atom and metal-induced effect on redox profile

Abstract

Extracted data

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