Progress of Atom Transfer Radical Polymerization (ATRP) Applied to the Synthesis of Star Polymers

综述了近10年来采用原子转移自由基聚合(ATRP)法合成星形聚合物的研究进展.从聚合单体、引发剂、聚合方法和反应条件以及聚合物性质等方面讨论了原子转移自由基聚合在星形聚合物合成中的应用,并根据聚合方法和引发剂对各种反应进行了分类.对原子转移自由基聚合技术在合成功能性复杂星形聚合物中的应用进行了展望.Star polymers synthesized by atom transfer radical polymerization ( ATRP) in recent ten years are reviewed. Atom transfer radical polymerization applied to synthesize star polymers are discussed in terms of monomers, initiators, methods of polymerization, condition of polymerization, and properties of products. Reactions are classified by polymeric approach and initiator. Application of ATRP technology to the synthesis of functional complex star polymers is predicted.中国科学院资助项目; 教育部科学技术基金http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000235098900020&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701SCI(E)中文核心期刊要目总览(PKU)中国科技核心期刊(ISTIC)中国科学引文数据库(CSCD)561089-10951