Synthesis, Structure and Thermal Property of [(n-C(16)H(33))N(CH(3))(3)](2)[TiF(6)]center dot 2H(2)O

刘国奇
李国宝
廖复辉
林建华

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Publication date

January 2008

DOI

10.1016/S1872-1508(08)60076-5

Publisher

物理化学学报

Journal

issn:1000-6818

Abstract

利用水热法在150℃合成了新的化合物六氟钛酸十六烷基三甲基胺二水合物([(n-C16H33)N(CH3)32[TiF6]·2H2O),并利用单晶X射线衍射技术解析了其结构,同时利用傅立叶变换红外光谱、元素分析及热分析技术加以佐证.该化合物由六氟钛酸根离子(TiF26-)、水分子及十六烷基三甲基胺离子([(n-C16H33)N(CH3)3]+)组成,属于单斜晶系,其空间群为C2/c.氢键在其构筑三维结构时起着重要的作用.A new compound dicetyltrimethylammonium hexafluorotitanium dihydrate, [(n-C(16)H(33))N(CH(3))(3)](2)[TiF(6)]center dot 2H(2)O (compound 1). was hydrothermally synthesized at 150 degrees C and characterized by single crystal X-ray diffraction, Fourier-transform infrared (FTIR) spectroscopy, elemental analysis, and thermogravimetric analysis. Compound 1 crystallizes in the monoclinic system, space group C2/c. It consists of hexafluorotitanium cations [TiF(6)](2-), water molecular (H(2)O), and cetyltrimethylammonium ions [(n-C(16)H(33))...

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Synthesis, Structure and Thermal Property of [(n-C(16)H(33))N(CH(3))(3)](2)[TiF(6)]center dot 2H(2)O

Abstract

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Synthesis, Structure and Thermal Property of [(n-C(16)H(33))N(CH(3))(3)](2)[TiF(6)]center dot 2H(2)O

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