N-H Bond Activation of Ammonia by Transition Metal and Main Group Element Complexes

NH3是一种在自然界生命过程及人类社会化学化工生产过程中非常重要的小分子.近年来,在过渡金属元素(如Ir,Rh,Ru,Fe,Pd等)及主族元素(如Si,Ge,Sn等)配合物活化NH3中N—H键的研究方面取得了一系列进展.介绍这方面研究的新成果.Activation of ammonia has received increasing attention in recent years due to its important role both in nature and industry processes. A series of transition metal (such as Ir, Rh, Ru, Fe, Pd, etc.) and main group element (such as Si, Ge, Sn, etc.) complexes have been reported to activate N-H bond of ammonia in the past three decades. This review includes the recent progresses in homogeneous N-H bond activation of ammonia by transition metal and main group element complexes.http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000318460600008&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701SCI(E)中文核心期刊要目总览(PKU)中国科技核心期刊(ISTIC)中国科学引文数据库(CSCD)204738-7483