研究了以癸烷为油相的十一烯酸癸胺正负离子表面活性剂体系对水的加溶作用.结果表明此体系在一定组成范围内可以形成均匀透明的反胶团或反相微乳液.升高温度和添加酸、碱、盐可以使形成反胶团或反相微乳的组成范围扩大.在正负离子表面活性剂中加入离子型表面活性剂、特别是负离子型表面活性剂,也有类似的作用.The solubilization of water in undecenoic acid - decyl amine/decane system has been investigated. A uniform and transparent liquid phase (L-2, reversed micellar phase or reversed microemulsion) can be formed in a range of composition. The increase of temperature or addition of acid or alkali or salt enlarged the L-2 area in phase diagram. Addition of ionic surfactants, especially anionic surfactants, into the catanionic surfactant systems has similar effect.国家自然科学基金; 教育部高校骨干教师资助计划http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:00016951...
Reverse micelle microemulsion systems are important in the field of materials science for their prev...
通过UV vis,1HNMR和TEM等方法研究了 [溴化十烷基三甲铵 (DTAB)与N (4 癸氧基 2 羟基苄基 )甘氨酸(C10 HG) ]正负离子表面活性剂混合体系中的正离子 π相互作用 ...
Surfactants are known for their ability to form self-assembled aggregates called micelles. Micelliza...
在1:1正负离子表面活性剂混合体系(十二烷基硫酸钠/辛基三甲基溴化铵SDS-C8NM3Br;十二烷基硫酸钠/十二烷基三甲基溴化铵,SDS-C12NM3Br)中加入短链脂肪醇(乙醇,正丙醇,正丁醇),正...
癸基三乙基溴化铵-癸基磺酸钠(C10NE-C10SO3)等摩尔混合均相体系(即使在表面活性剂总浓度高达0.2mol·L-1时仍然可形成稳定的均相溶液)在外加盐NaF、Na2SO4和Na3PO4的作用下...
根据所建议的表面活性剂疏水碳氢基在水溶液中自卷曲的分子构型和碳氢链/水界面自由能降低模型导出了对称正-负离子表面活性剂胶团化和表面吸附自由能及疏水自由能公式,计算结果支持上述理论模型。SCI(E)中国...
属于ABA型嵌段共聚物(A为聚氧乙烯,B为聚氧丙烯)的聚醚型表面活性剂分子在水中是否生成胶团,文献报道的结果迥异,临界胶团浓度值随测定方法不同出入很大.某些AB型或ABA型嵌段共聚物在选择性有机溶剂中...
本文研究高浓度区正、负离子表面活性剂混合胶团的形状及大小随浓度的变化规律.根据正、负离子表面活性剂混合体系的相行为,胶团溶液的光散射以及流变性质测量,提出了混合胶团的棒-球转变模型.认为在较高浓度,随...
Yüksek Lisans TeziBir mikroemülsiyonun oluşumu surfaktant tarafından yağ ve su arasındaki arayüzey g...
Molecular organized assemblies of 1:1 mixed solution of sodium alkylcarboxylate-alkyltrimethylammoni...
The behavior of water entrapped in reverse micelles (RMs) formed by two catanionic ionic liquid-like...
We report in this work on the scaling behavior of wormlike micelles formed in a series of mixed syst...
本文研究正负离子表面活性剂与两性表面活性剂混合水溶液的表面性质,以及两性表面活性剂对正负离子裘面活性剂溶解度的影响。结果表明:(1) 两性表面活性剂的加溶作用,有助于正负离子表面活性剂的溶解;(2) ...
对不同比例的下列表面活性剂混合物水溶液的表面张力作了测定:C_(10)H_(21)OSO_3Na(简称10CH)-C_(12)H_(25)OSO_3Na(简称12CH),C_7E_(15)COONa(...
测定了不同摩尔比的全氟辛酸钠(7CFNa)-十烷基硫酸钠(C_(10)SNa)混合水溶液(加NaCl,恒定离子强度μ=0.1m)的表面张力和界面张力(正庚烷-水溶液界面张力)。由表(界)面张力-浓度关...
Reverse micelle microemulsion systems are important in the field of materials science for their prev...
通过UV vis,1HNMR和TEM等方法研究了 [溴化十烷基三甲铵 (DTAB)与N (4 癸氧基 2 羟基苄基 )甘氨酸(C10 HG) ]正负离子表面活性剂混合体系中的正离子 π相互作用 ...
Surfactants are known for their ability to form self-assembled aggregates called micelles. Micelliza...
在1:1正负离子表面活性剂混合体系(十二烷基硫酸钠/辛基三甲基溴化铵SDS-C8NM3Br;十二烷基硫酸钠/十二烷基三甲基溴化铵,SDS-C12NM3Br)中加入短链脂肪醇(乙醇,正丙醇,正丁醇),正...
癸基三乙基溴化铵-癸基磺酸钠(C10NE-C10SO3)等摩尔混合均相体系(即使在表面活性剂总浓度高达0.2mol·L-1时仍然可形成稳定的均相溶液)在外加盐NaF、Na2SO4和Na3PO4的作用下...
根据所建议的表面活性剂疏水碳氢基在水溶液中自卷曲的分子构型和碳氢链/水界面自由能降低模型导出了对称正-负离子表面活性剂胶团化和表面吸附自由能及疏水自由能公式,计算结果支持上述理论模型。SCI(E)中国...
属于ABA型嵌段共聚物(A为聚氧乙烯,B为聚氧丙烯)的聚醚型表面活性剂分子在水中是否生成胶团,文献报道的结果迥异,临界胶团浓度值随测定方法不同出入很大.某些AB型或ABA型嵌段共聚物在选择性有机溶剂中...
本文研究高浓度区正、负离子表面活性剂混合胶团的形状及大小随浓度的变化规律.根据正、负离子表面活性剂混合体系的相行为,胶团溶液的光散射以及流变性质测量,提出了混合胶团的棒-球转变模型.认为在较高浓度,随...
Yüksek Lisans TeziBir mikroemülsiyonun oluşumu surfaktant tarafından yağ ve su arasındaki arayüzey g...
Molecular organized assemblies of 1:1 mixed solution of sodium alkylcarboxylate-alkyltrimethylammoni...
The behavior of water entrapped in reverse micelles (RMs) formed by two catanionic ionic liquid-like...
We report in this work on the scaling behavior of wormlike micelles formed in a series of mixed syst...
本文研究正负离子表面活性剂与两性表面活性剂混合水溶液的表面性质,以及两性表面活性剂对正负离子裘面活性剂溶解度的影响。结果表明:(1) 两性表面活性剂的加溶作用,有助于正负离子表面活性剂的溶解;(2) ...
对不同比例的下列表面活性剂混合物水溶液的表面张力作了测定:C_(10)H_(21)OSO_3Na(简称10CH)-C_(12)H_(25)OSO_3Na(简称12CH),C_7E_(15)COONa(...
测定了不同摩尔比的全氟辛酸钠(7CFNa)-十烷基硫酸钠(C_(10)SNa)混合水溶液(加NaCl,恒定离子强度μ=0.1m)的表面张力和界面张力(正庚烷-水溶液界面张力)。由表(界)面张力-浓度关...
Reverse micelle microemulsion systems are important in the field of materials science for their prev...
通过UV vis,1HNMR和TEM等方法研究了 [溴化十烷基三甲铵 (DTAB)与N (4 癸氧基 2 羟基苄基 )甘氨酸(C10 HG) ]正负离子表面活性剂混合体系中的正离子 π相互作用 ...
Surfactants are known for their ability to form self-assembled aggregates called micelles. Micelliza...