Self-Powered All-Inorganic Perovskite Microcrystal Photodetectors with High Detectivity

Organic–inorganic lead halide perovskite microcrystal (MC) films are attractive candidates for fabricating high-performance large-area self-powered photodetectors (PDs) because of their lower trap state density and higher carrier mobility than their polycrystalline counterparts and more suitability of synthesizing large lateral area films than their single-crystal counterparts. Here, we report on the fabrication of self-powered all-inorganic CsPbBr₃ perovskite MC PDs with high detectivity, using a modified solution synthesis method. The MCs are up to about 10 μm in size, and the MC layer is also about 11 μm in thickness. Under 473 nm laser (100 mW) illumination, the CsPbBr₃ MC PDs show responsivity values of up to 0.172 A W^–1, detectivity values of up to 4.8 × 10¹² Jones, on/off ratios of up to 1.3 × 10⁵, and linear dynamic ranges of up to 113 dB. These performances are significantly better than those of PDs based on polycrystalline perovskite thin films and comparable with those of PDs based on perovskite single crystals