By using a kinetic model based on the irreversible isomerizaticn of 5-hexenyl radical, the absolute rate constants for free-radical addition to 1,4-benzcquincne was determined (ka = (2.0 + 0.7).107 M-1 sec-1 at 69°C)
Free-radical interactions between hydroquinones (QH2) and ascorbate (AscH−) have a profound im...
Competitive kinetic experiments utilising free radical carbonylation chemistry provide a first estim...
The absolute rate constants for the addition of alkyl radicals to acrylonitrile and methyl acrylate ...
By using a kinetic model based on the irreversible isomerizaticn of 5-hexenyl radical, the absolute ...
The rate constants for the addition of the 5-hexenyl radical to styrene, a-methylstyrene, butadiene,...
The rate constants for the addition of the 5-hexenyl radical to styrene, \u3b1-methylstyrene, butadi...
Rate consts. were detd. for the addn. of 4-RC6H4• (R = H, MeO, Me, Cl, O2N) to 1,4-benzoquinone (I) ...
The rate constants for the homolytic alkylation of protonated heteroaromatic bases (4-methyl- and 4-...
The rate constants for the homolytic alkylation of protonated heteroaromatic bases (quinoline, pyrid...
The rate of coupling of alkyl radicals with the persistent aminoxyl radical 1,1,3,3-tetramethyl-isoi...
The absolute rate constants for the addition of alkyl radicals to styrene and acrylic monomers are d...
The absolute rate constants for the addition of alkyl radicals to styrene and acrylic monomers are d...
Free-radical interactions between hydroquinones (QH2) and ascorbate (AscH−) have a profound im...
Competitive kinetic experiments utilising free radical carbonylation chemistry provide a first estim...
The absolute rate constants for the addition of alkyl radicals to acrylonitrile and methyl acrylate ...
By using a kinetic model based on the irreversible isomerizaticn of 5-hexenyl radical, the absolute ...
The rate constants for the addition of the 5-hexenyl radical to styrene, a-methylstyrene, butadiene,...
The rate constants for the addition of the 5-hexenyl radical to styrene, \u3b1-methylstyrene, butadi...
Rate consts. were detd. for the addn. of 4-RC6H4• (R = H, MeO, Me, Cl, O2N) to 1,4-benzoquinone (I) ...
The rate constants for the homolytic alkylation of protonated heteroaromatic bases (4-methyl- and 4-...
The rate constants for the homolytic alkylation of protonated heteroaromatic bases (quinoline, pyrid...
The rate of coupling of alkyl radicals with the persistent aminoxyl radical 1,1,3,3-tetramethyl-isoi...
The absolute rate constants for the addition of alkyl radicals to styrene and acrylic monomers are d...
The absolute rate constants for the addition of alkyl radicals to styrene and acrylic monomers are d...
Free-radical interactions between hydroquinones (QH2) and ascorbate (AscH−) have a profound im...
Competitive kinetic experiments utilising free radical carbonylation chemistry provide a first estim...
The absolute rate constants for the addition of alkyl radicals to acrylonitrile and methyl acrylate ...