International audienceA Monte Carlo approach to radiative transfer in participating media is described and tested. It solves to a large extent the well known problem of Monte Carlo simulation of optically thick absorption configurations. The approach which is based on a net-exchange formulation and on adapted optical path sampling procedures is carefully designed to insure satisfactory convergence for all types of optical thicknesses. The need for such adapted algorithms is mainly related to the problem of gaseous line spectra representation in which extremely large ranges of optical thicknesses may be simultaneously encountered. The algorithm is tested against various band average computations for simple geometries using the Malkmus statis...