The asymmetric unit of the title compound, [Ni(C15H 14N3S2)2], consists of two independent molecules with similar configurations. Each Ni2+ cation is coordinated in a cis-mode by two tridentate N,N′,S-chelating Schiff base ligands, creating a distorted octa-hedron [the smallest angle being 77.57 (7)° and the widest being 168.97 (7)° for one molecule, and 78.04 (7) and 167.55 (7)° for the second molecule]. The dihedral angle between the mean coordination planes of the two ligands is 86.76 (7)° for one and 89.99 (7)° for the second molecule. π-π inter-actions between neighbouring pyridine rings with plane-to-plane distances of 3.540 (1) and 3.704 (1) Å are observed
The mononuclear neutral title complex, [Ni(NCS)2(C10H9N3)2], shows a cis-octahedral geometry around ...
The title compound, [Ni(C15H24NSi)2], is a homoleptic metal–η3-azaallyl centrosym...
The title compound, [Ni(C10H11N4O5)(2)], contains asymmetric Schiff base ligands, The coordination s...
The structure of the title compound, [Ni(C15H14N3S2)2]·H2O, has one molecule in the asymmetric unit...
In the crystal structure of the title compound, [Ni(C21H19N5O4S2)(C5H5N)2], the metal center is seve...
The asymmetric unit of the title complex, [Ni(NCS)2(C13H20N2O2)2], consists of two half-molecules, b...
The asymmetric unit of the title compound, (C14H15N2O2)[Ni(C6H4S2)2], contains one cation and two ha...
In the title complex, [Ni(C15H21N2S2)2], the NiII atom exhibits a square-planar coordination geometr...
In the asymmetric unit of the title complex, [Ni(C16H14N3OS)2], the nickel ion is tetracoordinated i...
The asymmetric unit of the title compound, (C13H11Cl2N2)2[Ni(C4N2S2)2], contains one-half of a centr...
In the asymmetric unit of the title complex, [Ni(C16H14N3OS)(2)], the nickel ion is tetracoordinated...
The asymmetric unit of the title ion-pair complex, (C9H12NO2)2[Ni(C4N2S2)2], contains two 1-(ethoxyc...
The asymmetric unit of the title complex, (C12H10N3)2[Ni(C4N2S2)2], consists of one 1-(4-cyanobenzyl...
R factor = 0.035; wR factor = 0.082; data-to-parameter ratio = 15.4. In the title compound, [Ni3(C10...
In the title compound, [Ni(NCS)2(C6H10N2)4]·C6H10N2, the asymmetric unit comprises a NiII c...
The mononuclear neutral title complex, [Ni(NCS)2(C10H9N3)2], shows a cis-octahedral geometry around ...
The title compound, [Ni(C15H24NSi)2], is a homoleptic metal–η3-azaallyl centrosym...
The title compound, [Ni(C10H11N4O5)(2)], contains asymmetric Schiff base ligands, The coordination s...
The structure of the title compound, [Ni(C15H14N3S2)2]·H2O, has one molecule in the asymmetric unit...
In the crystal structure of the title compound, [Ni(C21H19N5O4S2)(C5H5N)2], the metal center is seve...
The asymmetric unit of the title complex, [Ni(NCS)2(C13H20N2O2)2], consists of two half-molecules, b...
The asymmetric unit of the title compound, (C14H15N2O2)[Ni(C6H4S2)2], contains one cation and two ha...
In the title complex, [Ni(C15H21N2S2)2], the NiII atom exhibits a square-planar coordination geometr...
In the asymmetric unit of the title complex, [Ni(C16H14N3OS)2], the nickel ion is tetracoordinated i...
The asymmetric unit of the title compound, (C13H11Cl2N2)2[Ni(C4N2S2)2], contains one-half of a centr...
In the asymmetric unit of the title complex, [Ni(C16H14N3OS)(2)], the nickel ion is tetracoordinated...
The asymmetric unit of the title ion-pair complex, (C9H12NO2)2[Ni(C4N2S2)2], contains two 1-(ethoxyc...
The asymmetric unit of the title complex, (C12H10N3)2[Ni(C4N2S2)2], consists of one 1-(4-cyanobenzyl...
R factor = 0.035; wR factor = 0.082; data-to-parameter ratio = 15.4. In the title compound, [Ni3(C10...
In the title compound, [Ni(NCS)2(C6H10N2)4]·C6H10N2, the asymmetric unit comprises a NiII c...
The mononuclear neutral title complex, [Ni(NCS)2(C10H9N3)2], shows a cis-octahedral geometry around ...
The title compound, [Ni(C15H24NSi)2], is a homoleptic metal–η3-azaallyl centrosym...
The title compound, [Ni(C10H11N4O5)(2)], contains asymmetric Schiff base ligands, The coordination s...