The reaction of copper and silver cations with carbon dioxide was studied by mass-selected infrared photo-dissociation spectroscopy. Quantum chemical calculations were performed on these products, which aided the experimental assignments of the infrared spectra and helped to elucidate the geometrical and electronic structures. The Cu+ and Ag+ cations bind to an oxygen atom of CO2 in an end-on configuration via a charge-quadrupole electrostatic interaction in the [M(CO2)(n)](+) complexes. The formation of oxide-carbonyl and carbonyl-carbonate structures is not favored for the interaction of CO2 with Cu+ and Ag+. For n = 3 and 4, the n + 0 structure is preferred. [Note on the nomenclature: Using i + j, i denotes the number of CO2 molecules in...
Author Institution: Department of Chemistry, University of Georgia, Athens, GA 30602-2256Transition ...
Contains fulltext : 241411.pdf (Publisher’s version ) (Open Access
Density functional theory is employed to investigate the plasmon-driven CO2 reduction at the active ...
Anions are relevant in many different facets of chemistry. The study of anions, their interaction wi...
Converting carbon dioxide (CO2) into liquid fuels and synthesis gas is a world-wide priority. But th...
The mass-selected infrared photodissociation (IRPD) spectroscopy was utilized to investigate the int...
The mass-selected infrared photodissociation (IRPD) spectroscopy was utilized to investigate the int...
International audienceNew Infrared absorption data have been obtained using isolation in solid argon...
International audienceNew Infrared absorption data have been obtained using isolation in solid argon...
We report the results of an infrared photodissociation spectroscopy study to determine the structure...
Copper clusters on carbide surfaces have shown a high catalytic activity towards methanol formation...
We report the results of an infrared photodissociation spectroscopy study to determine the structure...
The structures of gas-phase M(+)(CO2)n (M = Co, Rh, Ir; n = 2-15) ion-molecule complexes have been i...
C–O bond breaking is an important process in the activation of \chem{CO_2} that can be catalyzed by ...
The CO2 electroreduction reaction (CO2RR) is a promising avenue to convert greenhouse gases into hig...
Author Institution: Department of Chemistry, University of Georgia, Athens, GA 30602-2256Transition ...
Contains fulltext : 241411.pdf (Publisher’s version ) (Open Access
Density functional theory is employed to investigate the plasmon-driven CO2 reduction at the active ...
Anions are relevant in many different facets of chemistry. The study of anions, their interaction wi...
Converting carbon dioxide (CO2) into liquid fuels and synthesis gas is a world-wide priority. But th...
The mass-selected infrared photodissociation (IRPD) spectroscopy was utilized to investigate the int...
The mass-selected infrared photodissociation (IRPD) spectroscopy was utilized to investigate the int...
International audienceNew Infrared absorption data have been obtained using isolation in solid argon...
International audienceNew Infrared absorption data have been obtained using isolation in solid argon...
We report the results of an infrared photodissociation spectroscopy study to determine the structure...
Copper clusters on carbide surfaces have shown a high catalytic activity towards methanol formation...
We report the results of an infrared photodissociation spectroscopy study to determine the structure...
The structures of gas-phase M(+)(CO2)n (M = Co, Rh, Ir; n = 2-15) ion-molecule complexes have been i...
C–O bond breaking is an important process in the activation of \chem{CO_2} that can be catalyzed by ...
The CO2 electroreduction reaction (CO2RR) is a promising avenue to convert greenhouse gases into hig...
Author Institution: Department of Chemistry, University of Georgia, Athens, GA 30602-2256Transition ...
Contains fulltext : 241411.pdf (Publisher’s version ) (Open Access
Density functional theory is employed to investigate the plasmon-driven CO2 reduction at the active ...