Integrated approach for identifying the factors controlling groundwater quality of a tropical coastal zone in Kerala, India

The present study examined the factors controlling shallow groundwater quality in two coastal panchayaths (viz., Chennam-Pallippuram and Thykkattussery) of Alappuzha district, Kerala, India, for three sampling seasons: pre-monsoon, monsoon and post-monsoon. The hydrochemical analysis shows significant seasonal fluctuations in groundwater quality, which are principally controlled by the climatic seasonality, contributed by the monsoon phenomenon. The groundwater is highly polluted due to organic load, which is manifested as high total and fecal coliform (TC and FC) contents, especially during MON. Fresh water recharge during MON contributes Ca–Mg–HCO3 type waters, whereas Ca–Mg–Cl and mixed cations-Cl types during PRM imply interaction between groundwater and saline/brackish water of the lake surrounding the study area. Such interaction is also evident by various ionic ratios (e.g., Mg2+/Ca2+, Na+/Cl−) as well as the correlation between Cl− and SO4 2−. The Ca2++ Mg2+ versus TZ+ relationship indicates significance of weathering of carbonate and silicate minerals as well as interaction between groundwater and aquifer matrix, which is also supported by the positive chloro-alkaline indices. Isotopic composition of the groundwater and lake water also suggests the influence of fresh water recharge (mainly during monsoon) as well as interaction of groundwater with lake water in controlling groundwater quality. Factor analysis proposes three dominant processes controlling groundwater quality of the region: (1) interaction of groundwater with brackish water of the Vembanad Lake, (2) geogenic/atmospheric sources, such as weathering, groundwater interaction with aquifer matrix, atmospheric inputs and fresh water recharge and (3) diverse anthropogenic sources of contamination (e.g., domestic waste, septic tanks, and agricultural residues). However, relative influence of these factors on groundwater quality varies temporally to form groundwater with differing chemical composition among the seasons. The present study underscores the exigency to ensure availability of safe drinking water for the coastal zones