We present the analysis performed on spectropolarimetric data of 97 O-type targets included in the framework of the Magnetism in Massive Stars (MiMeS) Survey. Mean least-squares deconvolved Stokes I and V line profiles were extracted for each observation, from which we measured the radial velocity, rotational and non-rotational broadening velocities, and longitudinal magnetic field B-l. The investigation of the Stokes I profiles led to the discovery of two new multiline spectroscopic systems (HD 46106, HD 204827) and confirmed the presence of a suspected companion in HD 37041. We present a modified strategy of the leastsquares deconvolution technique aimed at optimizing the detection of magnetic signatures while minimizing the detection of ...