Formation of a Uranium Trithiocarbonate Complex via the Nucleophilic Addition of a Sulfide-Bridged Uranium Complex to CS<sub>2</sub>
- Oanh P. Lam (2036044)
- Ludovic Castro (1472713)
- Boris Kosog (2059825)
- Frank W. Heinemann (1366557)
- Laurent Maron (1346082)
- Karsten Meyer (1321857)
Publication date
January 2012
DOIAbstract
The uranium(IV)/uranium(IV) μ-sulfide complex [{((<sup>Ad</sup>ArO)<sub>3</sub>N)U}<sub>2</sub>(μ-S)] reacts with CS<sub>2</sub> to form the trithiocarbonate-bridged complex [{((<sup>Ad</sup>ArO)<sub>3</sub>N)U}<sub>2</sub>(μ-κ<sup>2</sup>:κ<sup>2</sup>-CS<sub>3</sub>)]. The trithiocarbonate complex can alternatively be formed in low yields from low-valent [((<sup>Ad</sup>ArO)<sub>3</sub>N)U(DME)] through the reductive cleavage of CS<sub>2</sub>
Add to ORKG