Rhodium(III)-Catalyzed Hydroamination of Aromatic Terminal Alkynes with Anilines
- Elumalai Kumaran (1604614)
- Weng Kee Leong (1604617)
Publication date
February 2012
DOIAbstract
The dinuclear Rh(III) species [Cp*RhCl<sub>2</sub>]<sub>2</sub> catalyzes the hydroamination reaction between an aromatic terminal alkyne (ArCCH) and an aniline (Ar′NH<sub>2</sub>), in the presence of a salt additive, to afford the ketimine Ar′NC(Me)(Ar). A reaction pathway has been proposed on the basis of experimental and computational studies
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