A series of <i>p</i>-substituted benzhydryl fluorides (diarylfluoromethanes) were prepared and subjected to solvolysis reactions, which were followed conductometrically. The observed first-order rate constants <i>k</i><sub>1</sub>(25 °C) were found to follow the correlation equation log <i>k</i><sub>1</sub>(25 °C) = <i>s</i><sub>f</sub>(<i>N</i><sub>f</sub> + <i>E</i><sub>f</sub>), which allowed us to determine the nucleofuge-specific parameters <i>N</i><sub>f</sub> and <i>s</i><sub>f</sub> for fluoride in different aqueous and alcoholic solvents. The rates of the reverse reactions were measured by generating benzhydrylium ions (diarylcarbenium ions) laser flash photolytically in various alcoholic and aqueous solvents in the presence of flu...
A series of X,Y-substituted benzhydryl acetates (1-3) were subjected to solvolysis in various binary...
Konduktometrijskom metodom određene su brzine solvolize različito supstituiranih benzhidrilnih dieti...
Konduktometrijskom metodom određene su brzine solvolize različito supstituiranih benzhidrilnih dieti...
The specific rates of solvolysis of benzyl fluoroformate have been measured inseveral hydroxylic sol...
Abstract: The specific rates of solvolysis of benzyl fluoroformate have been measured in several hyd...
The specific rates of solvolysis of benzyl fluoroformate have been measured inseveral hydroxylic sol...
The leaving group ability (nucleofugality) of the pentafluorophenolate anion has been determined fro...
Rate constants and activations parameters are reported for solvolyses of p-Z-substituted benzoyl chl...
The specific rates of solvolysis of isobutyl fluoroformate (1) have been measured at 40.0 degrees C ...
The leaving group ability (nucleofugality) of the pentafluorophenolate anion has been determined fro...
The specific rates of solvolysis of isobutyl fluoroformate (1) have been measured at 40.0 °C in 22 p...
The specific rates of solvolysis of isobutyl fluoroformate (1) have been measured at 40.0 degrees C ...
Nucleofugalities of pentafluorobenzoate (PFB) and 2,4,6-trifluorobenzoate (TFB) leaving groups have ...
A series of X,Y-substituted benzhydryl acetates (1-3) were subjected to solvolysis in various binary...
A series of X,Y-substituted benzhydryl acetates (1-3) were subjected to solvolysis in various binary...
A series of X,Y-substituted benzhydryl acetates (1-3) were subjected to solvolysis in various binary...
Konduktometrijskom metodom određene su brzine solvolize različito supstituiranih benzhidrilnih dieti...
Konduktometrijskom metodom određene su brzine solvolize različito supstituiranih benzhidrilnih dieti...
The specific rates of solvolysis of benzyl fluoroformate have been measured inseveral hydroxylic sol...
Abstract: The specific rates of solvolysis of benzyl fluoroformate have been measured in several hyd...
The specific rates of solvolysis of benzyl fluoroformate have been measured inseveral hydroxylic sol...
The leaving group ability (nucleofugality) of the pentafluorophenolate anion has been determined fro...
Rate constants and activations parameters are reported for solvolyses of p-Z-substituted benzoyl chl...
The specific rates of solvolysis of isobutyl fluoroformate (1) have been measured at 40.0 degrees C ...
The leaving group ability (nucleofugality) of the pentafluorophenolate anion has been determined fro...
The specific rates of solvolysis of isobutyl fluoroformate (1) have been measured at 40.0 °C in 22 p...
The specific rates of solvolysis of isobutyl fluoroformate (1) have been measured at 40.0 degrees C ...
Nucleofugalities of pentafluorobenzoate (PFB) and 2,4,6-trifluorobenzoate (TFB) leaving groups have ...
A series of X,Y-substituted benzhydryl acetates (1-3) were subjected to solvolysis in various binary...
A series of X,Y-substituted benzhydryl acetates (1-3) were subjected to solvolysis in various binary...
A series of X,Y-substituted benzhydryl acetates (1-3) were subjected to solvolysis in various binary...
Konduktometrijskom metodom određene su brzine solvolize različito supstituiranih benzhidrilnih dieti...
Konduktometrijskom metodom određene su brzine solvolize različito supstituiranih benzhidrilnih dieti...